膜科学与技术

正渗透膜污染特征及抗污染正渗透膜研究进展

作者：王涛，王宁，陆金仁，王志宁，胡云霞

单位： 1. 中国科学院烟台海岸带研究所山东省环境工程研究中心中国科学院海岸带环境过程与生态修复重点实验室烟台 264003; 2. 中国海洋大学化学化工学院海洋化学理论与工程技术教育部重点实验室青岛 266100; 3. 中国海洋大学化学化工学院青岛 266100

关键词：正渗透；膜污染；抗污染；表面改性；共聚物

DOI号：

分类号： O631; TB34; TB43

出版年,卷(期):页码： 2017,37(1):125-132

摘要：

正渗透技术因其能耗低、水回收率高、截留能力强等优势，成为极具发展潜力的膜分离技术。然而，膜污染引起水通量持续下降，膜寿命缩短等问题严重制约了正渗透技术的发展和应用。如何有效控制膜污染已经成为正渗透技术亟需解决的问题。本综述从正渗透膜污染的角度出发，详细总结了正渗透的膜污染特征，全面介绍了抗污染正渗透膜的研究成果。通过对比众多的研究结果发现正渗透膜的性质、膜朝向、原料液性质以及膜过程操作条件是影响正渗透膜污染形成与清除的重要因素。通过优化操作条件虽然可部分减轻膜污染，但不能彻底解决膜污染问题。开发抗污染正渗透膜仍是根治膜污染的重要解决方案。本文最后详细介绍了目前抗污染正渗透膜的制备方法，包括双皮层结构正渗透膜的制备及结构调控、膜表面抗污染改性、开发抗污染亲水膜材料制备正渗透膜等。其中，新型两亲性共聚物作为支撑层材料展现出良好的发展潜力，是未来抗污染正渗透膜的发展方向。

Forward osmosis (FO) is a new membrane technology with great potential applications because of its low-energy consumption, high water recovery and great rejection. However, the continuous water flux decline and the shorten membrane life, caused by membrane fouling, have limited the further development of forward osmosis. How to effectively improve the membrane antifouling performance has become an important research topic. In this review, fouling characteristics of FO membrane is summarized, and the research progress of antifouled FO membranes is discussed. From literature, it can conclude that membrane properties, membrane orientation, pollutants and operating conditions are most important parameters to affect the fouling formation and membrane cleaning. Thus the development of anti-fouling forward osmosis membrane is crucial to mitigate membrane fouling. Double-skinned membrane structure, membrane surface modification, and the chosen antifouling membrane materials, have been confirmed to be effective strategies for FO membrane fouling prevention. Finally, in this review, the examples of how to improve the antifouling performance of FO membranes are discussed in details, and the promising research directions are pointed out to improve the membrane properties and antifouling performance of FO membranes.

基金项目：

国家自然科学基金委(No. 21476249)，山东省科技发展计划(No. 2014GHY115021)，和分离膜与膜过程国家重点实验室（天津工业大学）开放课题 (No. M1-201503)资助。

作者简介：

第一作者简介：王涛（1992-），男，山西省晋城市人，硕士生，研究方向为正渗透膜污染，E-mail: wangt329@163.com. *通讯作者， E-mail: yunxiahu@yic.ac.cn

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