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SiO2掺杂对四通道氧化铝中空纤维结构与性能的影响

作者：蔡超，张玉亭，王晓磊，顾学红

单位：南京工业大学材料化学工程国家重点实验室, 化工学院, 南京210009

关键词：中空纤维; 二氧化硅; 氧化铝; 莫来石

DOI号：

分类号： TQ028.8

出版年,卷(期):页码： 2017,37(1):1-7

摘要：

采用相转化和高温烧结相结合的方法制备四通道α-Al2O3中空纤维, 系统考察了SiO2掺杂含量对中空纤维结构与性能的影响. 结果表明, 1500 ºC煅烧温度下SiO2与Al2O3发生原位烧结反应生成莫来石相, 且莫来石相的含量随SiO2掺杂含量的增加而增大; SiO2掺杂含量的增加有利于提高中空纤维的纯水通量和孔隙率, 当SiO2掺杂含量达到20 mol%时, 中空纤维的纯水通量可达18.11 m3·m-2·h-1, 孔隙率为59.9%. 选用SiO2掺杂含量为20 mol%的中空纤维作为载体, 合成的中空纤维NaA分子筛膜用于90 wt.%乙醇/水渗透汽化分离, 75 ºC下膜的渗透通量高达21.21 kg·m-2·h-1.

Four-channel α-Al2O3 hollow fibers were fabricated by phase inversion and sintering method. Effects of SiO2 doping content on structure and property of hollow fiber were investigated. The results showed that mullite-phase was formed due to the in situ reaction between SiO2 and Al2O3 at 1500 ºC and its content enlarged with the SiO2 doping content. High pure water flux and porosity of hollow fiber were achieved under high SiO2 doping content. When the SiO2 doping content was 20 mol%, the pure water flux and porosity of as-prepared hollow fiber were 18.11 m3·m-2·h-1 and 59.9 %, respectively. Further, the hollow fiber owning a porosity of 59.9 % was used as support to prepare hollow fiber NaA zeolite membrane for pervaporation of 90 wt.% ethanol/water mixture. The permeation flux of the membrane was 21.21 kg·m-2·h-1 at 75 ºC.

基金项目：

国家自然科学基金(21222602, 21490585, 21176117); 国家863计划项目(2015AA03A602); 江苏省杰出青年基金项目(BK20122040); 江苏省自然科学基金青年基金项目(BK20130915); 江苏高校优势学科建设工程资助项目.

作者简介：

作者简介: 蔡超(1991-), 男, 江苏张家港人, 在读硕士, 从事膜材料制备与应用. *通讯联系人

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