关于超滤膜临界运行通量的探讨
作者:刘冲,吕晓龙,武春瑞,王暄,高启君,陈华艳,贾悦
单位: (分离膜与膜过程国家重点实验室,生物化工研究所,天津工业大学,天津 300387)
关键词: 膜污染;临界通量;临界运行通量
DOI号:
分类号: TQ028.3
出版年,卷(期):页码: 2017,37(1):23-26

摘要:
 临界通量一般被用于反映膜污染状态,但是临界通量对应的压力值偏小,不能完全反映实际过滤过程中的膜污染过程。按照我们提出的临界运行通量概念,本文将临界通量与临界运行通量进行了比较。通过考察无脉冲工艺、脉冲工艺和脉冲+硅藻土组合工艺的临界通量和临界运行通量,探讨二者反映膜污染的情况。结果表明,临界通量虽然可以表征三种工艺下膜污染状态的不同,但是由于此时滤饼层尚未形成,不能完全反映实际膜过滤过程中滤饼层的污染情况,临界通量数值缺乏实际指导意义。临界运行通量则较好地表征了实际膜过滤过程中的膜污染状态,更真实的反映滤饼层对膜通量的影响,与临界通量相比,临界运行通量对于实际工程应用更具实际指导意义。
 Critical flux was generally used to reflect the membrane fouling, but the pressure value corresponded critical flux was small, could not reflect the actual membrane fouling in filtrating process. According to our proposed the concept of critical operating flux, critical flux and critical operating flux were compared in this paper. Both two fluxes of the non-pulsation process, pulsation process and pulsation coupled with diatomite were investigated to discuss the case of reflecting the membrane fouling. The results showed that critical flux could show the difference of the membrane fouling state in the three process, but it was lack in the practical guiding significance because the actual membrane filtration process was done in a certain degree of cake layer. However, critical operating flux could better represent the actual state of membrane fouling in filtration process and reflect the influence of cake layer on membrane flux. Compared with critical flux, critical operating flux was sufficient in guiding significance in practical engineering applications.

基金项目:
国家自然科学基金(21176188,21576210)

作者简介:
第一作者简介:刘冲(1988-),男,河北沧州市人,硕士生,主要从事膜污染控制方法研究.*通讯作者,Email:luxiaolong@263.net

参考文献:
 [1] Curcio S, Scilingo G, Calabrò V, et al. Ultrafiltration of BSA in pulsating conditions: an artificial neural networks approach[J]. J.Membr.Sci, 2005, 246(2): 235-247.
[2] Schwinge J, Neal P R, Wiley D E, et al. Estimation of foulant deposition across the leaf of a spiral-wound module[J]. Desalination, 2002, 146(1): 203-208.
[3] Escobar I C, Van Der Bruggen B. Microfiltration and ultrafiltration membrane science and technology[J]. J.Appl.Polym.Sci, 2015, 132(21):1-17.
[4] Field R, Wu D, Howell J, et al. Critical flux concept for microfiltration fouling[J]. J.Membr.Sci, 1995, 100(3): 259-272.
[5] Chen V, Fane A, Madaeni S, et al. Particle deposition during membrane filtration of colloids: transition between concentration polarization and cake formation[J]. J.Membr.Sci, 1997, 125(1): 109-122.
[6] 姚金苗, 王湛, 梁艳莉, 等. 超, 微滤过程中临界通量的研究进展[J]. 膜科学与技术, 2008, 28(2): 69-72.
[7] 王兆之, 梁恒. 膜材料对阈通量的影响[J]. 给水排水, 2012, 38(11): 127-131.
[8] Defrance L, Jaffrin M. Comparison between filtrations at fixed transmembrane pressure and fixed permeate flux: application to a membrane bioreactor used for wastewater treatment[J]. J.Membr.Sci, 1999, 152(2): 203-210.
[9] Luo J, Ding L, Wan Y, et al. Threshold flux for shear-enhanced nanofiltration: experimental observation in dairy wastewater treatment[J]. J.Membr.Sci, 2012, 409: 276-284.
[10] Rai P, Rai C, Majumdar G, et al. Resistance in series model for ultrafiltration of mosambi (Citrus sinensis (L.) Osbeck) juice in a stirred continuous mode[J]. J.Membr.Sci, 2006, 283(1): 116-122.
 

服务与反馈:
文章下载】【加入收藏

《膜科学与技术》编辑部 地址:北京市朝阳区北三环东路19号蓝星大厦 邮政编码:100029 电话:010-64426130/64433466 传真:010-80485372邮箱:mkxyjs@163.com

京公网安备11011302000819号