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刺激响应膜及其研究进展

作者：黄晶¹，周晓吉¹，²，沈舒苏¹，²，杨晶晶¹，²，张干伟¹，²，白仁碧¹，²

单位：（1.苏州科技大学分离净化材料与技术研发中心，苏州 215009；2.江苏省水处理技术与协同创新中心，苏州 215009）

关键词：刺激响应膜；渗透性能；分离性能

DOI号：

分类号： TQ028.8

出版年,卷(期):页码： 2018,38(2):132-140

摘要：

刺激响应膜包括pH，温度，光、磁场、电场、离子强度等单一刺激响应膜或多重刺激响应膜。刺激响应膜通过改变它们的物理化学性质以对外界环境的变化作出响应，从而提供了一些独特的分离性能。本论文考察和总结了不同刺激响应膜性质的改变及其所造成的膜的渗透性能和分离性能等的变化，并展望了刺激响应膜的潜在应用及发展方向。

Stimuli-responsive membranes have been designed to respond to change in pH, temperature, light, magnetic field, electric and ionic strength. Stimuli-responsive membranes change their physicochemical properties in response to changes in their environment. This review covers the change of membrane properties which caused the alter of membrane permeability and separation performance. Finally, the potential applications and development in the future were discussed.

基金项目：

基金项目：国家自然科学基金项目（51478282）；苏州市分离净化材料与技术重点实验室（SZS201512）；苏州科技学院校科研基金项目（XKQ201502）；苏州科技学院研究生科研创新计划项目（SKCX16_033）

作者简介：

通讯作者：白仁碧 E-mail：ceebairb@live.com 作者简介：黄晶（1993-），女，湖北省鄂州市，在读硕士研究生，师承白仁碧教授，主要从事膜的改性研究。

参考文献：

[1]Wandera D, Wickramasinghe S R, Husson S M. Stimuli-responsive membranes[J]. J Membr Sci, 2010, 357 (1–2): 6–35.
[2]Chu L Y. Smart membrane materials and systems[M]. Zhejiang University Press Hangzhou and Springer-Verlag, Berlin Heidelberg, 2011, 27(12): 1069–1072.
[3]Ito Y, Park Y S, Imanishi Y. Visualization of critical pH-controlled gating of a porous membrane grafted with polyelectrolyte brushes[J]. J Am Chem Soc, 1997, 119(11): 2739–2740.
[4]Peng T, Cheng Y L. pH-responsive permeability of PE-g-PMAA membranes[J]. J Appl Polym Sci, 2000, 76(6): 778–789.
[5]Nunes S P, Behzad A R, Hooghan B, et al. Switchable pH-responsive polymeric membranes prepared via block copolymer micelle assembly[J]. ACS Nano, 2011, 5(5): 3516–3522.
[6]Iwata H, Oodate M, Uyama Y, et al. Preparation of temperature-sensitive membranes by graft polymerization onto a porous membrane[J]. J Membr Sci, 1991, 55(1–2): 119–130.
[7]Chu L Y, Park S H, Yamaguchi T, et al. Preparation of thermo-responsive core-shell microcapsules with a porous membrane and poly(N-isopropylacrylamide) gates[J]. J Membr Sci, 2001, 192(1–2): 27–39.
[8]Yuan X Y, Li W, Zhu Z G, et al. Thermo-responsive PVDF/PSMA composite membranes with micro/nanoscale hierarchical srtuctures for oil/water emulsion separation[J]. Colloids and Surfaces A: Physicochem, 2017, 516: 305–316.
[9]Chung D J, Imanishi Y. Preparation of porous membranes grafted with poly(spiropyran-containing methacrylate) and photo-control of permeability[J]. J Appl Polym Sci, 1994, 51(12): 2027–2033.
[10]Ly Y, Cheng Y L. Electrically-modulated variable permeability liquid crystal-line polymeric membrane[J]. J Membr Sci, 1993, 77(1): 99–112.
[11]Mika A M, Childs R F, Dickson J M, et al. A new class of polyelectrolyte-filled microfiltration membranes with environmentally controlled porosity[J]. J Membr Sci, 1995, 108(1–2): 37–56.
[12]Tokarev I, Minko S. Multiresponsive. Hierarchically structured membranes: new, challenging, biomimetic materials for biosensors, controlled release, biochemical gates, and nanoreactors[J]. Adv Mater, 2009, 21(2): 241–247.
[13]Stuart M A C, Huck W T S, Genzer J, et al. Emerging applications of stimuli responsive materials[J]. Nat Mater, 2010, 9(2): 101–113.
[14]Urban M W. Stratification, Stimuli-responsiveness, self-healing, and signaling in polymer networks[J]. Prog Polym Sci, 2009, 34 (8): 679–687.
[15]Qiu X, Yu H, Karunakaran M, et al. Peinemann, Selective separation of similarly sized proteins with tunable nanoporous block copolymer membranes[J]. ACS Nano 2012, 7(1): 768–776.
[16]Shi Q, Su Y, Ning X, et al. Graft polymerization of methacrylic acid onto polyether sulfone for potential pH-responsive membrane materials[J]. J Membr Sci, 2010, 347 (1–2): 62–68.
[17]Sinha M K, Purkait M K. Preparation and characterization of novel pegylated hydrophilic pH responsive polysulfone ultrafiltration membrane[J]. J Membr Sci, 2014, 464: 20–32.
[18]Schacher F, Ulbricht M, Müller A H E. Self-supporting, double stimuli-responsive porous membranes from polystyrene-block-poly(N,N-dimethylaminoethyl methacrylate) diblock copolymers[J]. Adv Funct Mater, 2009, 19(7): 1040–1045.
[19]Hester1 J F, Olugebefola S C, Mayes A M. Preparation of pH-responsive polymer membranes by self-organization[J]. J Membr Sci, 2002, 208 (1–2): 375–388.
[20]Ju J P, Wang C, Wang T M, et al. Preparation and characterization of pH-sensitive and antifoulingpoly(vinylidene fluoride) micro?ltration membranes blended withpoly(methyl methacrylate-2-hydrox -yethyl methacrylate-acrylic acid)[J]. J Colloid Interface Sci, 2014, 434: 175–180.
[21]Su Y L, Liu Y, Zhao X T, et al. Preparation of pH-responsive membranes with amphiphilic copolymers by surface segregation method[J]. Chin J Chem Eng, 2015, 23(8): 1283–1290.
[22]Wang M X, Yan F, Yan L Z, et al. Preparation and characterization of a pH-responsive membrane carrier for meso-tetraphenylsulfonato porphyrin[J]. RSC Adv, 2017, 7(3), 1687–1696.
[23]Yang B X, Xin Y G, Bai C L, et al. PVDF blended PVDF-g-PMAA pH-responsive membrane: Effect of additives and solvents on membrane properties and performance[J]. J Membr Sci, 2017, 541: 558–566。
[24]Chen L, Wu Y, Li Y Z, et al. pH-responsive poly(vinylidene fluoride) membranes containing a novel poly(vinylidene fluoride)-poly(acrylic acid) block copolymer blending material. Materials Letters,2018, 210:124-127.
[25]Zhao C, Nie S, Tang M. Polymer pH-sensitive membranes-A review. Sun, Prog. Polym. Sci. 2011, 36: 1499–1520.
[26]Weng X D, Bao X J, Jiang H D, et al. pH-responsive nanofiltration membranes containing carboxybetaine with tunable ion selectivity for charge-based separations. J. Membr. Sci, 2016, 520: 294–302.
[27]Tomicki F, Krix D, Nienhaus H, et al. Stimuli-responsive track-etched membranes via surface-initiated controlled radical polymerization: influence of grafting density and pore size[J]. J Membr Sci, 2011, 377(1–2), 124–133.
[28]Yao H, Wei D X, Che X M, et al. Comb-like temperature-responsive polyhydroxyalkanoate-graft-poly(2-dimethyamino-ethylmethacrylate)for controllable protein adsorption[J]. Polymer Chemistry, 2016, 7(38): 5957–5965.
[29]Chu L Y, Park S H, Yamaguchi T, et al. Preparation of thermo-responsive core-shell microcapsules with a porous membrane and poly(N-isopropylacrylamide) gates[J]. J Membr Sci, 2001, 192(1), 27–39.
[30]Yu J Z, Zhu L P, Zhu B K, et al. Poly((N-isopropylacrylamide) grafted poly(vinylidene fluoride) copolymers for temperature-sensitive membranes[J]. J Membr Sci, 2011, 366(1–2): 176–183.
[31]Friebe A, Ulbricht M. Controlled pore functionalization of poly(ethylene terpephthalate) track-etched membranes via surface-initiated atom transfer radical polymerization[J]. Langmuir 2007, 23(20): 10316–10322.
[32]Yang B., Yang W., Thermo-sensitive membranes regulated by pore-covering polymer brushes[J]. J Membr Sci, 2003, 218, 47–255.
[33]Alem H., Duwez A.S., Lussis P., Lipnik P. Jones A. M., Champagne S. D., Microstructure and thermo-responsive behavior of poly(Nisopropylacrylamide) brushes grafted in nanopores of track-etched membranes[J]. J Membr Sci, 2008, 308, 75-86.
[34]代正伟, 赵书梅, 薛元. PU/PNIPAM semi-IPN微孔膜温度响应性研究. 高分子学报，2012（5）：508-512.
[35]徐蒙, 张鹏, 陈琳, 等. BC/PNIPAM 温敏水凝胶的制备及其性能研究. 纤维素科学与技术，2017（2）。
[36]陈培珍，刘瑞来，饶瑞晔. 纤维素纳米纤维接枝聚（ N-异丙基丙烯酰胺）水凝胶的制备与表征。应用化学，2016（12）：1389-1395.
[37]Zhao Y, Zheng C, Wang Q, et al. Permanent and peripheral embolization: Temperature-sensitive p(N-isopropylacrylamide -co-butyl methylacrylate) nanogel as a novel blood-vessel-embolic material in the interventional therapy of liver tumors[J]. Advanced Functional Materials, 2011, 21(11): 2035-2042.
[38]Birkner M, Ulbricht M. Ultrafiltration membranes with markedly different pH- andion-responsivity by photografted zwitterionic polysulfobetain or polycarbobetain[J]. J Membr Sci, 2015, 494(2): 57–67.
[39]Zhao Y H, Wee K H, Bai R B. A novel electrolyte-responsive membrane with tunable permeation selectivity for protein purification[J]. Langmuir, 2010, 2(1): 203–211.
[40]Jia X, Wang J, Wang K, et al. Highly Sensitive Mechanochromic Photonic Hydrogels with Fast Reversibility and Mechanical Stability[J]. Langmuir, 2015, 31(31):8732.
[41]张晓栋, 秦立彦, 陈明清, 等. 镉离子响应性凝胶光子晶体传感膜的构建. Acta Phys, 2016, 32(12):2976—2982。
[42]Khoo M, Liu C. Micro magnetic silicone elastomer membrane actuator[J]. Sens.Actuators A, 2001, 89(3): 259–266.
[43]Yang Q, Himstedt Heath H, Ulbricht M, et al. Designing magnetic field responsive nanofiltration membranes[J]. J Membr Sci, 2013, 430(3): 70–78.
[44]Chen H, Palmese G R, Elabd Y A. Electrosensitive permeability of membranes with oriented polyelectrolyte nanodomins[J]. Macromolecules, 2007, 40 (4): 781–782.
[45]He D, Susanto H, Ulbricht M. Photo-irradiation, modification and stimulation of polymeric membranes[J]. Prog. Polym. Sci. 2009, 34(1): 62–98.
[46]Bera A, Kumar C U, Parui P, et al. Stimuli responsive and low fouling ultra?ltration membranes from blends of polyvinylidene ?uoride and designed library of amphiphilic poly(methyl methacrylate) containing copolymers[J]. J Membr Sci, 2015, 481: 137–147.
[47]Minoura N, Idei K, Rachkov A, et al. Preparation of azobenzene-containing polymer membranes that function in photo regulated molecular recognition[J]. Macromolecules, 2004, 37(25): 9571–9576.
[48]Shi W B, Deng J, Qin H, et al. Poly(ether sulfone) membranes with photo-responsive permeability[J]. J Membr Sci, 2014, 455(4): 357–367.
[49]Zhang L, Xu T W, Zhan L, et al. Controlled release of ionic drug through the positively charged temperature-responsive membranes[J]. J Membr Sci, 2006, 281: 491–499.
[50]Hoare T, Santamaria J, Goya G F, et al. A magnetically triggered composite membrane for on-demand drug delivery[J]. Nano letters, 2009, 9(10): 3651-3657.
[51]Hoare T, Timko B P, Santamaria J, et al. Magnetically triggered nanocomposite membranes: a versatile platform for triggered drug release[J]. Nano letters, 2011, 11(3): 1395-1400.
[52]Bordawekar M, Lipscomb GG, Escobar IC. Use of a Temperature Sensitive Surface Gel to Reduce Fouling[J]. Sep Sci Technol， 2009, 44: 3369–3391.
[53]Hsu C C, Wu C S, Liu Y L. Multiple stimuli-responsive poly(vinylidene ?uoride) (PVDF) membrane exhibiting high ef?ciency of membrane clean in protein separation[J]. J Membr Sci, 2014, 450: 257–264.
[54]Gajda M, Ulbricht M. Capillary pore membranes with grafted diblock copolymers showing reversibly changing ultrafiltration properties with independent response to ions and temperature[J]. J Membr Sci, 2016, 514: 510–517.
[55]Sinha M K, Purkait M K. Preparation and characterization of stimuli-responsive hydrophilic polysulfone membrane modified with poly (N-vinylcaprolactam-co-acrylic acid) [J]. Desalination, 2014, 348(12): 16–25.
[56]Chen Y C, Xie R, Chu L Y. Stimuli-responsive gating membranes responding to temperature, pH, salt concentration and anion species[J]. J Membr Sci, 2013, 442(9): 206–215.

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