膜科学与技术

气-液膜接触器法烟气脱硫脱硝的研究进展

作者：李颖娜¹，²，³ 张玉忠²，³ 吴楠⁴ 刘艳娟¹ 刘剑¹

单位： 1. 唐山学院环境与化学工程系，河北063000；2. 天津工业大学材料科学与工程学院, 天津 300387；3. 中空纤维膜材料与膜过程省部共建国家重点实验室（天津工业大学）, 天津 300387；4.河北出入境检验检疫局曹妃甸办事处，河北063000

关键词：气-液膜接触器；脱硫；脱硝；烟气

DOI号：

分类号： TQ534.9

出版年,卷(期):页码： 2018,38(5):137-144

摘要：

气-液膜接触器以其比表面积大、体积小、模块化设计与安装和易于放大规模等优点，有望替代传统的湿法烟气脱硫脱硝装置。本文对气-液膜接触器法烟气脱硫脱硝的研究进行了回顾，指出选择与开发高性能的吸收剂、构造合理的气-液膜接触器的结构、优化膜法烟气脱硫脱硝的操作工艺和烟气中同时脱硫脱硝等方面是气-液膜接触器法烟气脱硫脱硝领域的主要研究方向。

Gas-liquid membrane contactors for desulphurization and denitration from flue gas is likely to alternate to conventional desulphurization and denitration systems for its particular advantages such as small size, high surface area and modular. Important aspects of gas-liquid membrane contactor used in flue gas desulphurization and denitration including separation mechanism of the gas-liquid membrane contactor, liquid absorbents, module design of membrane contactor, technology optimization and simultaneous removal of gas-liquid membrane contactor for desulphurization and denitration from flue gas were discussed. It was also concluded that the research of activated liquid absorbents, the modules design of gas-liquid membrane contactors, the technology optimization of gas-liquid membrane contactor and the simultaneous removal of flue gas are the current and future investigation direction of desulphurization and denitration from flue gas with gas-liquid membrane contactor.

基金项目：

国家自然科学基金(21676201)；河北省科技计划项目（13273707,16211243）；河北省唐山市科技计划项目（14130238B），唐山学院项目（hhx2018003）

作者简介：

作者简介：李颖娜（1978-），女，河北省迁西县人，博士，高级实验师，从事材料改性和膜分离技术的研究，liyingna_2013@163.com

参考文献：

[1] Huang K, Lu J F, Wu Y T, et al. Absorption of SO2 in aqueous solutions of mixed hydroxylammonium dicarboxylate ionic liquids[J]. Chem Eng J, 2013, 215(2):36-44.
[2] 李颖娜，李涵，叶卉，等. 聚偏氟乙烯-氟化二氧化硅有机-无机复合膜的制备及脱硫性能[J]. 高分子材料科学与工程, 2017 , 33(2) :123-129.
[3] 马振,万皓.燃煤烟气同时脱硫脱硝方法的研究进展及分析[J].环境工程. 2017, 35 (2):78-82
[4] 常青,贾志谦,秦晋.膜气液接触过程的研究进展[J].膜科学与技术, 2012,32 (6):106-111.
[5] 李颖娜,张玉忠,陈颖.气-液膜接触器用膜材料的研究进展[J].高分子材料科学与工程,2014,30(8):178-184.
[6] Mansourizadeh A, Ismail A F. Hollow fiber gas-liquid membrane contactors for acid gas capture: A review [J]. J Hazard Mater, 2009, 171 (1):38-53.
[7] Mansourizadeh A. Experimental study of CO2 absorption/stripping via PVDF hollow fiber membrane contactor[J]. Chem Eng Res Des, 2012, 90 (4):555-562.
[8] 马宏勇.不同吸收剂黏度下孔隙率对膜吸收过程近膜壁面处溶质传质行为的影响[D].北京：北京化工大学，2012.
[9] Zhang H Y, Wang R, Liang D T, et al. Modeling and experimental study of CO2 absorption in a hollow fiber membrane contactor [J]. J Membr Sci, 2006,279 (1):301-310.
[10] Bottino A, Capannelli G, Comite A, et al. Separation of carbon dioxide from flue gases using membrane contactors [J]. Desalination, 2006,200 (1) :609-611.
[11] Yan S P, Fang M X, Zhang W F, et al. Experimental study on the separation of CO2 from flue gas using hollow fiber membrane contactors without wetting [J]. Fuel Process Technol, 2007, 88(5):501-511.
[12] Bottino A, Capannelli G, Comite A, et al. CO2 removal from a gas stream by membrane contactor [J]. Sep Purif Technol, 2008, 59 (1):85-90.
[13] Zhang H Y, Wang R, Liang D T, et al. Theoretical and experimental studies of membrane wetting in the membrane gas-liquid contacting process for CO2 absorption [J]. J Membr Sci, 2008, 308(1): 162-170.
[14] 王剑,张晓萍,李恩田,等. 膜法天然气脱硫的研究进展[J].环境工程, 2014,32(1):135-139.
[15] Dindore V Y, Versteeg G F. Gas-liquid mass transfer in a cross-flow hollow fiber module: analytical model and experimental validation [J]. Int J Heat Mass Transfer, 2005, 48(16):3352-3362.
[16] Liu L, Li L, Ding Z, et al. Mass transfer enhancement in coiled hollow fiber membrane modules [J]. J Membr Sci, 2005, 264(1):113-121.
[17] Asimakopoulou A G, Karabelas A J. A study of mass transfer in hollow-fiber membrane contactors-the　effect of fiber packing fraction[J]. J Membr Sci, 2006, 282(1):430-441.
[18] Li J L, Chen B H. Review of CO2 absorption using chemical solvents in hollow fiber membrane contactors [J]. Sep Purif Technol, 2005, 41(2):109-122.
[19] 吕月霞.聚丙烯中空纤维膜接触器分离CO2的研究[D].上海：华工理工大学，2011.
[20] 陈颖，关毅鹏，郭春刚.气-液膜接触器结构优化及其传质性能研究[J].膜科学与技术，2012,32(3):52-58.
[21] Zheng J M, Xu Z K, Li J M, et al. Influence of random arrangement of Hollow fiber membranes on shell side mass transfer performance:a novel model prediction[J]. J Membr Sci, 2004, 236(1):145-151.
[22] 张卫凤,方梦祥,晏水平,等.不同中空纤维膜接触器分离烟气中CO2的性能比较[J].动力工程, 2007,27 (4):606-610.
[23] Naim R, Ismail A F. Effect of fiber packing density on physical CO2 absorption performance in gas-liquid membrane contactor[J]. Sep Purif Technol, 2013, 115(1):152-157.
[24] 陈颖,关毅鹏,张召才,郭春刚.海水烟气脱硫膜吸收单元及工艺研究[J].膜科学与技术,2011,31(5):58-63.
[25] Jani J M, Wessling M, Lammertink R G H. Geometrical influence on mixing in helical porous membrane microcontactors[J]. J Membr Sci, 2011, 378(1):351-358.
[26] Boributh S, Assabumrungrat S, Laosiripojana N, et al. Effect of membrane module arrangement of gas-liquid membrane contacting process on CO2 absorption performance:a modeling study[J]. J Membr Sci, 2011,372 (1):75-86.
[27] Boributh S, Rongwong W, Assabumrungrat S. Mathematical modeling and cascade design of hollow fiber membrane contactor for CO2 absorption by monoethanolamine[J]. J Membr Sci, 2012, 401-402(19):175-189.
[28] 陈迁乔,钟秦.微孔中空纤维膜接触器烟气脱硫性能的研究[J].高校化学工程学报, 2010,24 (1):144-149.
[29] Park H H, Deshwal B R, Kim I W, et al. Absorption of SO2 from flue gas using PVDF hollow fiber membranes in a gas-liquid contactor[J]. J. Membr. Sci., 2008, 319(1):29-37.
[30] Park H H, Deshwal B R, Jo H D, et al. Absorption of nitrogen dioxide by PVDF hollow fiber membranes in a G-L contactor[J].Desalination, 2009,243(1):52-64.
[31] 陆建刚.酸性气体（CO2/H2S）的脱除及其气液传质特性的研究[D]. 南京：南京理工大学，2005.
[32] Esquiroz-Molina A, Georgaki S, Stuetz R. Influence of pH on gas phase controlled mass transfer in a membrane contactor for hydrogen sulphide absorption [J]. J Membr Sci, 2013, 427(1) :276-282.
[33] 陆建刚,陈敏东,徐建强. 溶液环境中疏水性聚丙烯膜结构性能的变化[J]. 南京理工大学学报(自然科学版), 2009,33 (6):820-823.
[34] 陆建刚,花爱春,刘士鑫. 膜吸收工艺中溶液对聚丙烯膜结构和形态的影响[J]. 南京理工大学学报(自然科学版), 2011,35(5):726-730.
[35] Luis P, Garea A, Irabien A. Zero solvent emission process for sulfur dioxide recovery using a membrane contactor and ionic liquids[J]. J Membr Sci, 2009, 330(1):80-89.
[36] 孙雪雁,杨凤林. 膜吸收法海水脱硫研究[J].膜科学与技术,2008,28(1):66-71.
[37] 陈颖,郭春刚,刘国昌,等. 脱硫海水膜法曝气恢复试验研究[J].水处理技术, 2013,39 (2):107-111.
[38] Sun X Y, Meng F G, Yang F L. Application of seawater to enhance SO2 removal from simulated flue gas through hollow fiber membrane contactor [J]. J Membr Sci, 2008, 312(1) 6-14.
[39] 陈迁乔,钟秦.微孔中空纤维膜接触器烟气脱硫性能的研究[J].高校化学工程学报,2010,24 (1):144-149.
[40] 马玉慧,叶卉,张玉忠,等.聚醚砜中空纤维膜接触器脱硫性能研究[J].膜科学与技术, 2016 , 36(5) :60-67.
[41] Yu H S , Thé J, Tan Z C, et al. Modeling SO2 absorption into water accompanied with reversible reaction in a hollow fiber membrane contactor[J]. Chem Eng Sci, 2016,156 (2):136-146.
[42] Hosseinzadeh A, Hosseinzadeh M, Vatani A, et al. Mathematical modeling for the simultaneous absorption of CO2 and SO2 using MEA in hollow fiber membrane contactors[J]. Chem Eng Process,2016,111 (1)：35-45.
[43] Rami F, Al-Marzouqi M. Mathematical modeling for the simultaneous absorption of CO2 and H2S using MEA in hollow fiber membrane contactors [J]. J Membr Sci, 2009, 342(1):269-278.
[44] 韩粉女,钟秦. K2Cr2O7溶液同时脱硫脱硝实验研究[J].环境污染与防治,2012,34 (5):6-9.
[45] Li S G, Rocha D J, Zhou S J. Post-combustion CO2　capture using super-hydrophobic, polyether ether ketone, hollow fiber membrane contactors [J]. J Membr Sci, 2013, 430(3):79-86.
[46] 方平,岑超平,唐志雄,等. 尿素/H2O2溶液同时脱硫脱硝机理研究[J].燃料化学学报,2012,40(1):111-118.
[47] Zhang L, Qu R M, Sha Y, et al. Membrane gas absorption for CO2 capture from flue gas containing fine particles and gaseous contaminants [J]. Int J Greenh Gas Con, 2015, 33(33): 10-17.
[48] 关毅鹏,陈颖,张召才,等. 膜吸收法烟气同时脱硫脱硝试验研究[J].膜科学与技术,2014,34(1):111-115.

服务与反馈：

【文章下载】【加入收藏】

《膜科学与技术》编辑部地址：北京市朝阳区北三环东路19号蓝星大厦邮政编码：100029 电话：010-64426130/64433466 传真：010-80485372邮箱：mkxyjs@163.com