聚合物包容膜及其在萃取分离中研究进展 |
作者:陆雅萌1,2,王建英1,王朵3,张恒2,王勇2 |
单位: 1. 河北科技大学化学与制药工程学院,河北石家庄 050018 |
关键词: 聚合物包容膜;塑化剂;基础聚合物;膜萃取;溶剂萃取 |
DOI号: |
分类号: TQ051.8+93 |
出版年,卷(期):页码: 2020,40(5):136-143 |
摘要: |
聚合物包容膜(PIM)是一种在支撑液膜(SLM)分离体系基础上发展的新型萃取用膜,主要由基础聚合物、萃取剂和塑化剂等聚合而成。由于PIM膜具有稳定性高、使用寿命长、操作简便和成本较低等优点,逐渐受到研究者的关注。本文介绍了聚合物包容膜的组成、制备方法、萃取分离原理,并根据聚合物包容膜中基础聚合物的不同,综述了近年来聚合物包容膜在萃取分离方面的研究进展。同时,对聚合物包容膜在分离领域的应用进行了展望。 |
Polymer inclusion membrane (PIM) is a new type of the liquid membrane developed from the supporting liquid membrane (SLM). Due to their exceptional stability, ease of operation and cost advantage, PIM has attracted more and more attention recently. In this paper, we hence strived to overview-the composition, preparation process and separation mechanism of the PIM system. In particular, the applications of the PIMs composed of different polymers were classified and introduced. The comprehensive information generates valuable insights into the prospective applications of PIMs in the determination and separation of metal ions and small organic molecules in a myriad of chemical engineering fields. |
基金项目: |
国家重点研发计划资助(2019YFC1907700),中国科学院科技服务网络计划(STS)KFJ-STS-QYZD-081 |
作者简介: |
陆雅萌(1995-),女,河北石家庄,硕士研究生,分离科学与工程,E-mail:Yameng_Lu@163.com |
参考文献: |
[1] 袁承业. 溶剂萃取应用的新进展[J]. 化学通报, 1977, (02):22-32+46. [2] 曹明帅, 黄万抚, 胡昌顺. 乳化液膜分离中破乳技术研究进展[J]. 应用化工, 2019, 48(04):922-925. [3] 李莹雪, 崔崇威. 支撑液膜技术对金属离子的分离回收[J]. 膜科学与技术, 2015, 35(04):89-96. [4] Bloch R, Finkelstein A, Kedem O, et al. Metal-ion separation by dialysis through solvent membranes[J]. Ind Eng Chem Proc Dd, 1967, 6(2):231-+. [5] Nghiem L D, Mornane P, Potter I D, et al. Extraction and transport of metal ions and small organic compounds using polymer inclusion membranes (PIMs)[J]. J Membrane Sci, 2006, 281(1-2):7-41. [6] Almeida M I G S, Silva A M L, Coleman R A, et al. Development of a passive sampler based on a polymer inclusion membrane for total ammonia monitoring in freshwaters[J]. Anal Bioanal Chem, 2016, 408(12):3213-3222. [7] Fontas C, Tayeb R, Tingry S, et al. Transport of platinum(IV) through supported liquid membrane (SLM) and polymeric plasticized membrane (PPM)[J]. J Membrane Sci, 2005, 263(1-2):96-102. [8] Tayeb R, Fontas C, Dhahbi M, et al. Cd(II) transport across supported liquid membranes (SLM) and polymeric plasticized membranes (PPM) mediated by Lasalocid A[J]. Sep Purif Technol, 2005, 42(2):189-193. [9] Wang D, Hu J G, Li Y, et al. Evidence on the 2-nitrophenyl octyl ether (NPOE) facilitating copper (II) transport through polymer inclusion membranes[J]. J Membrane Sci, 2016, 501:228-235. [10] Almeida M I G S, Cattrall R W, Kolev S D. Recent trends in extraction and transport of metal ions using polymer inclusion membranes (PIMs)[J]. J Membrane Sci, 2012, 415:9-23. [11] 靳俏俏. PVC/D2EHPA聚合物包容膜分离输运苯胺及几种阳离子染料的研究[D]. 北京: 北京化工大学, 2017. [12] Pereira N, St John A, Cattrall R W, et al. Influence of the composition of polymer inclusion membranes on their homogeneity and flexibility[J]. Desalination, 2009, 236(1-3):327-333. [13] 付伟佳. 基于PVDF-HFP复合聚合物电解质的性能研究[D]. 安徽: 合肥工业大学, 2019. [14] Kaya A, Onac C, Alpoguz H K, et al. Reduced graphene oxide based a novel polymer inclusion membrane: Transport studies of Cr(VI)[J]. J Mol Liq, 2016, 219:1124-1130. [15] Kolev S D, Sakai Y, Cattrall R W, et al. Theoretical and experimental study of palladium(II) extraction from hydrochloric acid solutions into Aliquat 336/PVC membranes[J]. Anal Chim Acta, 2000, 413(1-2):241-246. [16] Wang L J, Paimin R, Cattrall R W, et al. The extraction of cadmium(II) and copper(II) from hydrochloric acid solutions using an Aliquat 336/PVC membrane[J]. J Membrane Sci, 2000, 176(1):105-111. [17] Garcia-Rodriguez A, Fontas C, Matamoros V, et al. Development of a polymer inclusion membrane-based passive sampler for monitoring of sulfamethoxazole in natural waters. Minimizing the effect of the flow pattern of the aquatic system[J]. Microchem J, 2016, 124:175-180. [18] Upitis A, Peterson J, Lukey C, et al. Metallic ion extraction using polymer inclusion membranes (PIMs): Optimising physical strength and extraction rate[J]. Desalin Water Treat, 2009, 6(1-3):41-47. [19] O’Bryan Y, Cattrall R W, Truong Y B, et al. The use of poly(vinylidenefluoride-co-hexafluoropropylene) for the preparation of polymer inclusion membranes application to the extraction of thiocyanate[J]. J Membrane Sci, 2016:S0376738816301545. [20] Yildiz Y, Manzak A, Tutkun O. Selective extraction of cobalt ions through polymer inclusion membrane containing Aliquat 336 as a carrier[J]. Desalin Water Treat, 2016, 57(10):4616-4623. [21] Kozlowski C A, Walkowiak W. Removal of chromium(VI) from aqueous solutions by polymer inclusion membranes[J]. Water Res, 2002, 36(19):4870-4876. [22] Salazar-Alvarez G, Bautista-Flores A N, Miguel E R D, et al. Transport characterisation of a PIM system used for the extraction of Pb(II) using D2EHPA as carrier[J]. J Membrane Sci, 2005, 250(1-2):247-257. [23] Konczyk J, Kozlowski C, Walkowiak W. Removal of chromium(III) from acidic aqueous solution by polymer inclusion membranes with D2EHPA and Aliquat 336[J]. Desalination, 2010, 263(1-3):211-216. [24] Wang D, Hu J G, Liu D B, et al. Selective transport and simultaneous separation of Cu(II), Zn(II) and Mg(II) using a dual polymer inclusion membrane system[J]. J Membrane Sci, 2017, 524:205-213. [25] Tor A, Arslan G, Muslu H, et al. Facilitated transport of Cr(III) through polymer inclusion membrane with di(2-ethylhexyl)phosphoric acid (DEHPA)[J]. J Membrane Sci, 2009, 329(1-2):169-174. [26] Sharaf M, Yoshida W, Kubota F, et al. A polymer inclusion membrane composed of the binary carrier PC-88A and Versatic 10 for the selective separation and recovery of Sc[J]. Rsc Advances, 2018, 8(16):8631-8637. [27] Mahanty B N, Mohapatra P K, Raut D R, et al. Polymer inclusion membrane containing a diglycolamide-functionalized calix[4]arene for actinide ion uptake and transport[J]. J Membrane Sci, 2016, 516:194-201. [28] Kim J S, Kim S K, Ko J W, et al. Selective transport of cesium ion in polymeric CTA membrane containing calixcrown ethers[J]. Talanta, 2000, 52(6):1143-1148. [29] Baba Y, Kubota F, Goto M, et al. Separation of cobalt(II) from manganese(II) using a polymer inclusion membrane with N-[N,N-di(2-ethylhexyl)aminocarbonylmethyl]glycine (D2EHAG) as the extractant/carrier[J]. Journal of Chemical Technology & Biotechnology, 2016, 91(5):1320-1326. [30] O'Bryan Y, Truong Y B, Cattrall R W, et al. A new generation of highly stable and permeable polymer inclusion membranes (PIMs) with their carrier immobilized in a crosslinked semi-interpenetrating polymer network. Application to the transport of thiocyanate[J]. J Membrane Sci, 2017, 529. [31] Hoque B, Almeida M I G S, Cattrall R W, et al. Effect of cross-linking on the performance of polymer inclusion membranes (PIMs) for the extraction, transport and separation of Zn(II)[J]. J Membrane Sci, 2019, 589. [32] Eduardo R D S M, de Gyves J. Metal Ion Separations by Supported Liquid Membranes[J]. Industrial & Engineering Chemistry Research, 1999, 38(6):2182-2202. [33] Cussler E L, Aris R, Bhown A, et al. On the limit of facilitated diffusion[J]. J Membrane Sci, 1989, 43(2-3):149-164. [34] White K M, Smith B D, Duggan P J, et al. Mechanism of facilitated saccharide transport through plasticized cellulose triacetate membranes[J]. J Membrane Sci, 2001, 194(2):165-175. [35] Gherasim C V, Bourceanu G, Olariu R I, et al. A novel polymer inclusion membrane applied in chromium (VI) separation from aqueous solutions[J]. J Hazard Mater, 2011, 197:244-253. [36] Saf A O, Alpaydin S, Coskun A, et al. Selective transport and removal of Cr(VI) through polymer inclusion membrane containing 5-(4-phenoxyphenyl)-6H-1,3,4-thiadiazin-2-amine as a carrier[J]. J Membrane Sci, 2011, 377(1-2):241-248. [37] Argiropoulos G, Cattrall R W, Hamilton I C, et al. The study of a membrane for extracting gold(III) from hydrochloric acid solutions[J]. J Membrane Sci, 1998, 138(2):279-285. [38] 高晨光. 聚合物包容膜对水相中苯酚的传输富集研究[D]. 西安: 西安建筑科技大学, 2015. [39] St John A M, Cattrall R W, Kolev S D. Extraction of uranium(VI) from sulfate solutions using a polymer inclusion membrane containing di-(2-ethylhexyl) phosphoric acid[J]. J Membrane Sci, 2010, 364(1-2):354-361. [40] Kubota F, Kono R, Yoshida W, et al. Recovery of gold ions from discarded mobile phone leachate by solvent extraction and polymer inclusion membrane (PIM) based separation using an amic acid extractant[J]. Sep Purif Technol, 2019, 214:156-161. [41] Ershad M, Almeida M I G S, Spassov T G, et al. Polymer inclusion membranes (PIMs) containing purified dinonylnaphthalene sulfonic acid (DNNS): performance and selectivity[J]. Sep Purif Technol, 2018, 195:446-452. [42] Schow A J, Peterson R T, Lamb J D. Polymer inclusion membranes containing macrocyclic carriers for use in cation separations[J]. J Membrane Sci, 1996, 111(2):291-295. [43] Pospiech B. Application of phosphonium ionic liquids as ion carriers in polymer inclusion membranes (PIMs) for separation of cadmium(II) and copper(II) from aqueous solutions[J]. J Solution Chem, 2015, 44(12):2431-2447. [44] Gardner J S, Walker J O, Lamb J D. Permeability and durability effects of cellulose polymer variation in polymer inclusion membranes[J]. J Membrane Sci, 2004, 229(1-2):87-93. [45] Guo L, Liu Y H, Zhang C, et al. Preparation of PVDF-based polymer inclusion membrane using ionic liquid plasticizer and Cyphos IL 104 carrier for Cr(VI) transport[J]. J Membrane Sci, 2011, 372(1-2):314-321. [46] Guo L, Zhang J P, Zhang D L, et al. Preparation of poly(vinylidene fluoride-co-tetrafluoroethylene)-based polymer inclusion membrane using bifunctional ionic liquid extractant for Cr(VI) transport[J]. Ind Eng Chem Res, 2012, 51(6):2714-2722. [47] Wang D, Cattrall R W, Li J, et al. A poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP)-based polymer inclusion membrane (PIM) containing LIX84I for the extraction and transport of Cu(II) from its ammonium sulfate/ammonia solutions[J]. J Membrane Sci, 2017, 542:272-279. [48] Croft C F, Almeida M I G S, Cattrall R W, et al. Separation of lanthanum(III), gadolinium(III) and ytterbium(III) from sulfuric acid solutions by using a polymer inclusion membrane[J]. J Membrane Sci, 2018, 545. [49] Yoshida W, Baba Y, Kubota F, et al. Selective transport of scandium(III) across polymer inclusion membranes with improved stability which contain an amic acid carrier[J]. J Membrane Sci, 2019, 572. |
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