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基于石墨烯量子点TFN膜的制备与性能

作者：欧阳果仔，李新冬，张鑫，袁佳彬，李海柯，李浪，李文豪，钟招煌，黄万抚

单位： 1江西理工大学赣州市赣江流域水质安全保障技术创新中心，江西赣州 341000； 2江西理工大学赣州市流域污染模拟与控制重点实验室，江西赣州 341000

关键词：石墨烯量子点；TFN；界面聚合；纳滤；修饰

DOI号：

分类号： TQ052；X799.3

出版年,卷(期):页码： 2021,41(2):41-50

摘要：

利用哌嗪（PIP）与均苯三甲酰氯（TMC）的界面聚合反应将石墨烯量子点（GQDs）作为水相添加剂掺入到纳滤膜分离皮层中构成薄层纳米复合（TFN）膜，并采用傅里叶变换红外光谱（FTIR）、X射线光电子能谱（XPS）、扫描电子显微镜（SEM）、原子力显微镜（AFM）、Zeta电位、水接触角等手段进行了表征分析。研究发现即使水相中加入的GQDs含量较低，但GQDs-PA-TFN膜的表面结构、荷负电性和亲水性能均得到了有效地改善。同时为了保证GQDs-PA-TFN膜对小分子物质的高效截留，在不牺牲膜渗透通量的情况下进行了二次界面聚合反应。当GQDs添加量为0.003 wt%，在实验得到的最佳反应条件下制备的GQDs-PA-TFN膜在0.6 MPa压力下渗透通量为36.9 L/m2•h，是未添加GQDs的TFC膜的1.4倍，对MgSO4的截留率为95.8 %。

Graphene quantum dots (GQDs) was incorporated into the separation functional layer as an aqueous additive by interfacial polymerization of piperazine (PIP) and trimesoyl chloride (TMC) to preparation TFN membrane. The samples were characterized by fourier transform infrared spectroscopy (FTIR), x-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), atomic force microscope (AFM), Zeta potential and water contact angle. It was found that the surface structure, electronegativity and hydrophilicity of the GQDs-PA-TFN membrane were effectively improved even though the content of GQDs in the aqueous phase was low. At the same time, in order to ensure the efficient interception of small molecules by GQDs-PA-TFN membrane, the secondary interfacial polymerization reaction was carried out without sacrificing the flux of the TFN membrane. With the addition of GQDs at 0.003 wt%, the permeation of the GQDs-PA-TFN membrane prepared under the optimal reaction conditions obtained by the experiment reached 36.9 L/m2•h under the pressure of 0.6 MPa, which was 1.4 times that of the TFC membrane without GQDs, and the rejection of MgSO4 was 95.8%.

基金项目：

江西省教育厅科技项目（GJJ160619）；国家级大学生创新创业训练项目（201910407009）；江西省研究生创新专项资金项目（YC2020-S456）

作者简介：

欧阳果仔（1995-），男，江西吉安，硕士生，膜法水处理技术，E-mail: oy08192571@163.com

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