膜科学与技术

位置：首页 >> 期刊内容阅读

膜法制糖技术研究现状、挑战与展望

作者：刘露露，罗建泉，张昊，陈向荣，万印华

单位：生化工程国家重点实验室，中国科学院过程工程研究所，中国科学院大学，北京 100190

关键词：蔗汁；糖蜜；浓缩液；膜污染；膜清洗

DOI号：

分类号： TQ050.4

出版年,卷(期):页码： 2021,41(2):140-146

摘要：

膜法制糖技术通过分离膜精确的物理筛分作用将蔗汁中的非糖成分逐级去除，从而实现蔗糖产品的绿色化和多样化制备，有望变革传统化学制糖工艺。本文综述了膜法制糖技术的最新研究进展，首先简要介绍了针对甘蔗汁、原糖回溶糖浆和糖蜜三种不同原料的膜法制糖工艺，然后重点阐述了膜法制糖技术大规模应用存在的难点及其相关研究成果，主要包括膜浓缩液处理、膜污染控制和清洗。最后对膜法制糖技术的未来研究方向进行展望，为该技术的工业化应用提供理论指导。

Membrane-based sugar production technology removes the non-sugar components in cane juice step by step through the precise physical sieving effect of the separation membranes, thereby realizing the green and diversified preparation of cane sugar products, which is expected to replace the traditional chemical sugar production processes. This article reviews the latest research progress of sugar production by membrane technology. First, it briefly introduces three membrane-based sugar production processes for different feeds, such as sugarcane juice, raw sugar remelting syrup and molasses. Then the main bottleneck problems for large-scale application of membrane technology in sugar production are emphasized, mainly including membrane concentrate treatment, membrane fouling control and cleaning, and the relevant research outcomes (e.g. diafiltration for sucrose recovery from the concentrate, pretreatment, membrane modification, threshold flux concept for fouling control, two-step chemical or enzymatic cleaning) are also reviewed. Finally, the future research directions of membrane-based sugar production technology are prospected to provide theoretical guidance for its industrial applications.

基金项目：

中国科学院科技服务网络计划（STS计划）区域重点项目（KFJ-STS-QYZX-096）

作者简介：

刘露露（1996-），女，贵州福泉人，博士研究生，从事膜法制糖技术研究. E-mail：llliu_gz@163.com.

参考文献：

[1]罗春雄. 优先发展农业农村决战决胜脱贫攻坚认真贯彻落实2019年中央一号文件精神[J]. 广西经济, 2019, (3):35,38-39.
[2]罗建泉, 杭晓风, 刘威, 等. 膜法绿色制糖技术研究进展[J]. 过程工程学报, 2018, 18(05):908-917.
[3]Nene S, Kaur S, Sumod K, et al. Membrane distillation for the concentration of raw cane-sugar syrup and membrane clarified sugarcane juice[J]. Desalination, 2002, 147(1):157-160.
[4]Wittwer S. Applications for stainless steel crossflow membranes in sugar processing[A]. Symposium on Advanced Technology for raw sugar and cane and beet refined sugar production, 1999, 9-10.
[5]李文, 朱瓌之, 漆虹, 等. 陶瓷膜超滤净化石灰法制糖清汁[J]. 食品科学, 2019, 40(2):252-258.
[6]Li W, Ling G Q, Shi C R, et al. Pilot demonstration of ceramic membrane ultrafiltration of sugarcane juice for raw sugar production[J]. Sugar Tech, 2016, 19(1):83-88.
[7]Vu T, LeBlanc J, Chou C. Clarification of sugarcane juice by ultrafiltration membrane: Toward the direct production of refined cane sugar[J]. J Food Eng, 2020, 264:109682.
[8]Susanto H, Roihatin A, Widiasa I N. Production of colorless liquid sugar by ultrafiltration coupled with ion exchange[J]. Food Bioprod Process, 2016, 98:11-20.
[9]Luo J, Hang X, Zhai W, et al. Refining sugarcane juice by an integrated membrane process: Filtration behavior of polymeric membrane at high temperature[J]. J Membr Sci, 2016, 509:105-115.
[10]Saska M. Method for Producing White Sugar[P]. US Patent, US6096136A. 2000-08-01.
[11]王健, 陈花山, 王宝, 等. 我国精炼糖厂发展现状、问题及对策[J]. 中国糖料, 2020, 42(03):73-80.
[12]Li W, Ling G, Huang P, et al. Performance of ceramic microfiltration membranes for treating carbonated and filtered remelt syrup in sugar refinery[J]. J Food Eng, 2016, 170:41-49.
[13]Fu X, Yu S, Chung C. Application of ultrafiltration membrane system in refined cane sugar process[J]. Journal of South China University of Technology (Natural Science Edition), 2003, 31(11):5-9.
[14]李美玲, 王卓琳, 黎庆涛, 等. 甘蔗最终糖蜜制备原色食用糖浆及抗氧化性分析[J]. 中国调味品, 2019, 44(8):84-88.
[15]Qi B, Wu Y, Guo S, et al. Refinement of cane molasses with membrane technology for clarifcation and color removal[J]. J Membr Sci Res, 2017, 3(4):303-307.
[16]Luo J, Guo S, Wu Y, et al. Separation of sucrose and reducing sugar in cane molasses by Nanofiltration[J]. Food Bioprocess Technol, 2018, 11(5):913-925.
[17]Wang J, Luo J, Ren Y, et al. From molasses to syrup: Engineering ultrafiltration membrane surface to improve invertase reusability[J]. J Membr Sci, 2020, 610:118287.
[18]Saha N K, Balakrishnan M, Ulbricht M. Fouling control in sugarcane juice ultrafiltration with surface modified polysulfone and polyethersulfone membranes[J]. Desalination, 2009, 249(3):1124-1131.
[19]罗建泉, 万印华, 杭晓风, 等. 一种膜法制糖工艺中多联产的方法[P]. 北京, CN201910277336.5. 2019-05-31.
[20]罗建泉, 万印华. 一种全组分利用的甘蔗制糖系统及其处理方法[P]. 北京, CN201710367609.6. 2018-04-20.
[21]杭方学, 詹景亭, 黄苏婷, 等. 陶瓷膜过滤甘蔗汁浓缩液透析回收糖分实验研究[J]. 中国调味品, 2018, 43(11):12-16,22.
[22]Jacob S, Jaffrin M Y. Purification of brown cane sugar solutions by ultrafiltration with ceramic membranes: investigation[J]. Sep Sci Technol, 2020, 35(7):989.
[23]Jegatheesan V, Phong D D, Shu L, et al. Performance of ceramic micro- and ultrafiltration membranes treating limed and partially clarified sugar cane juice[J]. J Membr Sci, 2008, 327(1-2):69-77.
[24]Saha N K, Balakrishnan M, Ulbricht M. Polymeric membrane fouling in sugarcane juice ultrafiltration: role of juice polysaccharides[J]. Desalination, 2006, 189(1-3):59-70.
[25]Li Y, Luo J, Wan Y. Biofouling in sugarcane juice refining by nanofiltration membrane: Fouling mechanism and cleaning[J]. J Membr Sci, 2020, 612:118432.
[26]Vercellotti J R, Clarke M A, Godshall M A. Sugarcane components that affect efficiency of membrane filtration: identification and removal[A]. International Society of Sugarcane Technologists, 1999.
[27]Saha N K, Balakrishnan M, Ulbricht M. Sugarcane juice ultrafiltration: FTIR and SEM analysis of polysaccharide fouling[J]. J Membr Sci, 2007, 306(1):287-297.
[28]罗建泉, 万印华, 杭晓风. 一种面向机械化收割的甘蔗混合汁膜法清净预处理方法[P]. 北京, CN201710117704.0. 2018-04-20.
[29]宋伟杰, 万印华, 罗建泉. 一种利用多级膜过滤技术精制甘蔗混合汁的制糖工艺[P]. 北京, CN201510486534.4. 2015-11-18.
[30]Qiang X, Luo J, Guo S, et al. A novel process for molasses utilization by membrane filtration and resin adsorption[J]. J Clean Prod, 2019, 207:432-443.
[31]杨强剑, 罗建泉, 郭世伟, 等. 聚醚砜超滤膜处理糖蜜中的膜污染控制[J]. 膜科学与技术, 2019, 39(6):94-102.
[32]Guo S, Luo J, Wu Y, et al. Decoloration of sugarcane molasses by tight ultrafiltration: Filtration behavior and fouling control[J]. Sep Purif Technol, 2018, 204:66-74.
[33]Yang Q, Luo J, Guo S, et al. Threshold flux in concentration mode: fouling control during clarification of molasses by ultrafiltration[J]. J Membr Sci, 2019, 586:130-139.
[34]Luo J, Morthensen S T, Meyer A S, et al. Filtration behavior of casein glycomacropeptide (CGMP) in an enzymatic membrane reactor: fouling control by membrane selection and threshold flux operation[J]. J Membr Sci, 2014, 469(6):127-139.
[35]Luo J, Guo S, Qiang X, et al. Sustainable utilization of cane molasses by an integrated separation process: Interplay between adsorption and nanofiltration[J]. Sep Purif Technol, 2019, 219:16-24.
[36]黄嘉臣, 罗建泉, 郭世伟, 等. 化学清洗对聚酰胺纳滤膜的影响机制研究进展[J]. 膜科学与技术, 2020, 40(1):188-195.
[37]Li W, Ling G, Lei F, et al. Ceramic membrane fouling and cleaning during ultrafiltration of limed sugarcane juice[J]. Sep Purif Technol, 2018, 190:9-24
[38]Akhtar A, Senthilmurugan S, Mohanty K, et al. Sugarcane juice clarification by lanthanum phosphate nanofibril coated ceramic ultrafiltration membrane: PPO removal in absence of lime pre-treatment, fouling and cleaning studies[J]. Sep Purif Technol, 2020, 249:117157.

服务与反馈：

【文章下载】【加入收藏】

《膜科学与技术》编辑部地址：北京市朝阳区北三环东路19号蓝星大厦邮政编码：100029 电话：010-64426130/64433466 传真：010-80485372邮箱：mkxyjs@163.com