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聚乙烯亚胺改性多壁碳纳米管用于制备高通量复合纳滤膜

作者：黑云皓，项军，田桂英，唐娜

单位： 1.天津科技大学化工与材料学院，天津 300457；2.天津市卤水化工与资源生态化利用重点实验室，天津 300457

关键词：多壁碳纳米管；聚乙烯亚胺改性；水通量；纳滤；截留率；

DOI号：

分类号： TQ028.8

出版年,卷(期):页码： 2021,41(5):87-96

摘要：

本文以聚砜（PSF）超滤膜为基膜，聚乙烯亚胺（PEI）为水相单体，均苯三甲酰氯（TMC）为有机相单体，将聚乙烯亚胺改性的多壁碳纳米管（MWCNTs-PEI）添加进水相中，采用界面聚合法制备了有机无机杂化复合纳滤膜。分析和表征了改性多壁碳纳米管的微观形貌、化学性质和分散性质及由其改性后的纳滤膜的微观结构、红外光谱和接触角，讨论了MWCNTs-PEI添加量对膜性能的影响。结果表明，当改性多壁碳纳米管的添加量为100mg·L-1时，制备的复合纳滤膜水通量能达到11.95L·m−2·h−1·bar−1，MgCl2的截留率为94.4%。同时，该复合纳滤膜对四种常见的商业染料的截留率均约为98%。

In this work, polyethyleneimine modified multi-walled carbon nanotubes were prepared, polysulfone ultrafiltration membrane, polyethyleneimine and trimesoyl chloride were as the base membrane, water phase monomer, and organic phase monomer, respectively. Modified multi-walled carbon nanotubes were added into the water phase, and the organic-inorganic hybrid composite nanofiltration membrane was prepared by the interfacial polymerization method. The microscopic morphology/chemical properties and dispersion properties of the modified multi-walled carbon nanotubes were analyzed and characterized. The microstructure, infrared spectrum and contact angle of the base membrane and nanofiltration membrane were analyzed and characterized, and the influence of the addition amount of polyethyleneimine modified multi-walled carbon nanotubes on the membrane performance was discussed. The results show that the water flux of the composite nanofiltration membrane with 100mg·L-1 modified multi-walled carbon nanotubes can reach 11.95L·m−2·h−1·bar−1, and the rejection rate of MgCl2 is 94.4%. At the same time, the rejection rate for the four common commercial dyes is about 98%.

基金项目：

国家自然科学基金(U20A20148)，天津市科技项目计划(18YFZCSF00330)，教育部科研创新团队培育计划(IRT-17R81)，天津市高等学校创新团队培养计划(TD13-5008)

作者简介：

黑云皓（1995-），男，天津，硕士研究生，从事纳滤膜制备与膜法水处理研究，E-mail：18722460197@163.com.

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