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含薄荷酯的手性共轭微孔聚合物混合基质膜的制备及其对映体拆分性能

作者：谢禹杰，藏雨，王建军，徐亮，张转芳，黄媛，崔嘉，雷天阳，荆博宇，苗凤娟

单位： 1.齐齐哈尔大学材料科学与工程学院，黑龙江齐齐哈尔 161006；2.齐齐哈尔大学分析测试中心，黑龙江齐齐哈尔 161006；3.齐齐哈尔大学通信与电子工程学院，黑龙江齐齐哈尔 161006

关键词：薄荷酯；共轭微孔聚合物；混合基质膜；对映体分离

DOI号：

分类号： TQ317；TQO28.8

出版年,卷(期):页码： 2022,42(2):78-88

摘要：

采用“自下而上”策略，成功合成了2种含薄荷酯的手性共轭微孔聚合物（CCMP）。以CCMP为分散相，醋酸纤维素（CA）、乙基纤维素（EC）为基质，采用相转换法，制备了3种混合基质膜。扫描电子显微镜显示，CCMP在基质中分散均匀。在氨基酸外消旋体的对映体分离时，当分散相CDCMP-1质量分数为4％，混合基质膜对(D,L)-苯丙氨酸的透过率为7.75×10-9 m2/h，对映体过量为60.6％ee，表现出较高的对映体分离性能。

In this paper, two kinds of chiral conjugated microporous polymers (CCMP) containing menthol esters were successfully synthesized by the "bottom-up" strategy. Using CCMP as dispersed-phase, cellulose acetate (CA) and ethyl cellulose (EC) as substrates, three mixed-matrix membranes were prepared by phase conversion method.Scanning electron microscopy showed that CCMP was evenly dispersed in the matrix.When the mass fraction of CDCMP-1 was 4%, the permeability of (D,L) -phenylalanine was 7.75×10-9 m2/h, and the excess of enantiomer was 60.6% ee, showing high enantiomer separation performance.

基金项目：

国家自然科学基金（52173202）；2019黑龙江省省属本科高校基本科研业务费青年创新人才项目（135409201）；黑龙江省自然科学基金（JQ20197003,ZD20197004）

作者简介：

谢禹杰（1997-），男，河南省洛阳市，硕士研究生在读，研究方向为分离功能高分子膜

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