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基于金属有机骨架（MOFs）的纳滤膜制备研究现状

作者：杜海洋，张文娟，温书，常晶，王少坡，张宇峰

单位：天津城建大学环境与市政工程学院水质科学与技术天津市重点实验室，天津 300384

关键词：混合基质膜；纳滤膜；金属有机骨架（MOFs）；TFN膜

DOI号：

分类号： TQ028;TB333

出版年,卷(期):页码： 2022,42(2):154-162

摘要：

纳滤膜的渗透和截留性能相互制约。金属有机骨架（MOFs）材料因其具有大孔隙率、高比表面积和孔径可调控的特点受到广泛关注，将MOFs作为纳米颗粒添加剂引入纳滤膜中，可有效缓解膜的选择性和渗透性之间的制约效应，并且赋予了纳滤膜一些其他的特点，如亲（疏）水性、抗菌性及抗污染性。本文介绍了应用于纳滤膜中MOFs的分类、特性及合成方法，列举了近些年来在MOFs纳滤膜中几种常用的聚合物基底，包括聚偏氟乙烯、聚砜、聚醚砜、聚酰亚胺和聚丙烯腈，并对制备MOFs纳滤膜的一些方法，主要是原位生长法、共混法以及界面聚合法等进行了详细的阐述。最后总结了在研究MOFs纳滤膜过程中遇到的一些问题，并对今后MOFs纳滤膜的发展做出了展望。

The permeability and retention of nanofiltration membrane restrict each other. Metal organic frameworks (MOFs) materials have attracted much attention because of their large porosity, high specific surface area and controllable pore size. Introducing MOFs as a nanoparticle additive into nanofiltration membrane can effectively alleviate the restriction effect between membrane selectivity and permeability, and endow the nanofiltration membrane with some other characteristics, such as hydrophilicity, antibacterial and anti-fouling. In this paper, the classification, characteristics and synthesis methods of MOFs used in nanofiltration membranes are introduced, and several polymer substrates commonly used in MOFs nanofiltration membranes in recent years are listed, including polyvinylidene fluoride, polysulfone, polyethersulfone, polyimide and polyacrylonitrile. Some methods for the preparation of MOFs nanofiltration membranes, such as in-situ growth, blending and interfacial polymerization, are described in detail. Finally, some problems encountered in the research of MOFs nanofiltration membrane are summarized, and the development of MOFs nanofiltration membrane in the future is prospected.

基金项目：

国家自然科学基金（52100011）；天津市教委科研计划项目（2018KJ161），天津城建大学科研启动基金（180501412）

作者简介：

杜海洋(1997-)，男，河北沽源人，硕士，研究方向为基于金属有机骨架纳滤膜的制备

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