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多孔配位有机硅在膜分离领域中的应用

作者：谭先先，余亮，冯霄，王博

单位：北京理工大学，北京100081

关键词：配位单元；有机硅；膜分离技术

DOI号：

分类号： TQ028.8

出版年,卷(期):页码： 2023,43(5):159-167

摘要：

多孔配位有机硅材料是一类兼具Si-O-Si网络骨架和配位单元的复合材料，由于具有较高的孔隙率、孔径和孔分布易调节及孔道环境易修饰等优点，使其在重金属吸附和检测、自修复材料和膜分离技术等领域展现出了广阔的应用前景。本文主要介绍多孔配位有机硅材料的分类、制备方法及其在膜分离技术领域的应用研究进展。

Porous coordinated organosilica is a class of composite materials with both Si-O-Si amphomous network and coordination unit. Owing to their outstanding properties, such as high-level porosity, adjustable pore size and pore size distribution, and the tailor-made chemistry of pore walls, porous coordinated organosilica has demonstrated a broad range of applications in adsorption and detection of heavy metals, self-healing materials and membrane separation. This review mainly introduces the classification and preparation approaches of porous coordinated organosilica and pays a special attention in the research progress of their pioneer applications in membrane separation.

基金项目：

国家自然科学基金（21971017，22171022）

作者简介：

谭先先（1999-），女，广西贵港人，主要研究方向：E-mail：3120201296@bit.edu.cn

参考文献：

[1] 王湛, 王志, 高学理, 等. 膜分离技术基础[M]//北京: 化学工业出版社, 2000:1－6.
[2] Robeson L M. Correlation of separation factor versus permeability for polymeric membranes[J]. J. Membr. Sci., 1991, 62(2):165－185.
[3] Robeson L M. The upper boud revisited[J]. J. Membr. Sci., 2008, 320(1-2):390－400.
[4] Kanezashi M, Yada K, Yoshioka T, et al. Design of silica networks for development of highly permeable hydrogen separation membranes with hydrothermal stability[J]. J. Am. Chem. Soc., 2009, 131(2):414－415.
[5] Ren X X, Tsuru T. Organosilica-based membranes in gas and liquid-phase separation[J]. Membranes, 2019, 9(9):107－131.
[6] 廖明佳, 朱韵, 任秀秀, 等. 微孔桥联有机硅杂化膜的制备方法及影响因素研究进展[J]. 膜科学与技术, 2021, 41(2): 147－156.
[7] Guo M, Kanezashi M, Nagasawa H, et al. Pore subnano-environment engineering of organosilica membranes for highly selective propylene/propane separation[J]. J. Membr. Sci., 2020, 603:117999.
[8] Gong G H, Nagasawa H, Kanezashi M, et al. Facile and scalable flow-induced deposition of organosilica on porous polymer supports for reverse osmosis desalination[J]. ACS Appl. Mater. Interfaces, 2018, 10(16):14070－14078.
[9] Zhang H, Wen J, Shao Q, et al. Fabrication of La/Y-codoped microporous organosilica membranes for high-performance pervaporation desalination[J]. J. Membr. Sci., 2019, 584:353－363.
[10] Kanezashi M, Yoneda Y, Nagasawa H, et al. Gas permeation properties for organosilica membranes with different Si/C ratios and evaluation of microporous structures[J]. AIChE J., 2017, 63(10):4491－4498.
[11] Guo M, Kanezashi M, Nagasawa H, et al. Amino-decorated organosilica membranes for highly permeable CO2 capture[J]. J. Membr. Sci., 2020, 611:118328.
[12] Kanezashi M, Miyauchi S, Nagasawa H, et al. Gas permeation properties through Al-doped organosilica membranes with controlled network size[J]. J. Membr. Sci., 2014, 466:246－252.
[13] Yu L, Kanezashi M, Hiroki Nagasawa, et al. Tailoring ultramicroporosity to maximize CO2 transport within pyrimidine-bridged organosilica membranes[J]. ACS Appl. Mater. Interfaces, 2019, 11:7164－7173.
[14] Batten S R, Champness N R, Chen X, et al. Terminology of metal–organic frameworks and coordination polymers[J]. Pure Appl. Chem., 2013, 85(8):1715－1724.
[15] O’Keeffe M, Yaghi O M. Deconstructing the crystal structures of metal organic frameworks and related materials into their underlying nets[J]. Chem. Rev., 2012, 112(2):675－702.
[16] Schoedel A, Li M, Li D, et al. Structures of metal−organic frameworks with rod secondary building units[J]. Chem. Rev., 2016, 116(19):12466－12535.
[17] 钱彬彬，李娜，常泽，等. 多孔配位聚合物：发展历程及研究进展[J]. 中国科学：化学, 2019, 49(11): 1361-1376.
[18] Czaja A U, Trukhan N, Müller U. Industrial applications of metal-organic frameworks[J]. Chem. Soc. Rev., 2009, 38(5):1284－1293.
[19] Kalaj M, Bentz K C, Ayala S Jr, et al. MOF-Polymer hybrid materials: from simple composites to tailored architectures[J]. Chem. Rev., 2020, 120(16):8267－8302.
[20] Kitao T, Zhang Y, Kitagawa S, et al. Hybridization of MOFs and polymers[J]. Chem. Soc. Rev., 2017, 46(11):3108－3133.
[21] 周玲玲, 牛照栋, 汤立红, 等. MOFs有机-无机杂化膜的制备及应用研究进展[J]. 膜科学与技术, 2018, 38(6):111－120.
[22] El-Nahhal I M, El-Ashgar N M. A review on polysiloxane-immobilized ligand systems: Synthesis, characterization and applications[J]. J. Organomet. Chem., 2007, 692(14):2861－2886.
[23] Gao M, Han S, Hu Y, et al. Enhanced fluorescence in tetraylnitrilomethylidyne-hexaphenyl derivative-functionalized periodic mesoporous organosilicas for sensitive detection of copper(II)[J]. J. Phys. Chem. C, 2017, 120(17):9299－9307.
[24] 项雪莲. 有机硅高分子与金属配合物的合成及发光性能的研究[D]. 山东:山东大学, 2012.
[25] Li C, Wang C, Keplinger C, et al. A highly stretchable autonomous self-healing elastomer[J]. Nat. Chem., 2016, 8(6):618－624.
[26] 王琳琳, 李磊, 冯圣玉. 有机硅超分子材料研究进展[J]. 高等学校化学学报, 2021, 42(7):2111－2122.
[27] Rao Y, Chortos A, Pfattner R, et al. Stretchable self-healing polymeric dielectrics cross-linked through metal-ligand coordination[J]. J Am. Chem. Soc., 2016, 138(18):6020－6027.
[28] Anggarini U, Tsuru T, Kanezashi M, et al. Metal-induced microporous aminosilica creates a highly permeable gas-separation membrane[J]. Mater. Chem. Front., 2021, 5(7):3029－3042.
[29] Anggarini U, Yu L, Nagasawa H, et al. Microporous nickel-coordinated aminosilica membranes for improved pervaporation performance of methanol/toluene separation[J]. ACS Appl. Mater. Interfaces, 2021, 13(19):23247－23259.
[30] Mendezvivar J, Mendoza-Serna R, Bosch P, et al. Influence of isoeugenol as a chelating agent on the structure of Si–Ti polymeric systems obtained from alkoxides[J]. J. Non-Cryst. Solids, 1999, 248(2-3):147－158.
[31] 陈雨雁. 聚倍半硅氧烷/金属-有机框架杂化材料的制备与性能研究[D]. 山东:山东大学, 2020.
[32] 赵亚云. 基于有机硅超薄管膜的制备及其气体分离性能研究[D]. 浙江：中国科学院大学(中国科学院宁波材料技术与工程研究所), 2020.
[33] Kong C, Du H, Chen L, et al. Nanoscale MOF/organosilica membranes on tubular ceramic substrates for highly selective gas separation[J]. Energy Environ. Sci., 2017, 10:1812－1819.
[34] 严浩军, 张帅, 杜红斌, 等. 一种ZIF-8/有机硅杂化膜的制备及性能研究[J]. 膜科学与技术, 2019, 39(1):9－15.
[35] He D, Zhang H, Ren Y，et al. Fabrication of a novel microporous membrane based on ZIF-7 doped 1,2-bis(triethoxysilyl)ethane for H2/CO2 separation [J]. Microporous Mesoporous Mater., 2022, 331:111674.
[36] Fukumoto T, Yoshioka T, Nagasawa, H, et al. Development and gas permeation properties of microporous amorphous TiO2–ZrO2–organic composite membranes using chelating ligands[J]. J. Membr. Sci., 2014, 461:96－105.
[37] Lawal S, Kanezashi M, Nagasawa H, et al. Development of an acetylacetonate-modified silica-zirconia composite membrane applicable to gas separation[J]. J. Membr. Sci., 2020, 599(3):117844.
[38] Besselink R, Qureshi H F, Winnubst L, et al. A novel malonamide bridged silsesquioxane precursor for enhanced dispersion of transition metal ions in hybrid silica membranes[J]. Microporous Mesoporous Mater., 2015, 214:45－53.
[39] Anggarini U, Yu L, Nagasawa H, et al. Metal-induced aminosilica rigidity improves highly permeable microporous membranes via different types of pendant precursors[J]. ACS Appl. Mater. Interfaces, 2022, 14(37):42692－42704.
[40] Anggarini U, Nagasawa H, Kanezashi M, et al. Structural two-phase evolution of aminosilica-based silver-coordinated membranes for increased hydrogen separation[J]. J. Membr. Sci.,2022, 642:119962.
[41] 侯影飞, 许杨, 李海平, 等. 渗透汽化膜改性技术研究进展[J]. 膜科学与技术, 2018, 38(01):136－142.
[42] 周宗尧, 张朔, 王宁, 等. 有机溶剂分离膜技术研究进展[J]. 膜科学与技术, 2018, 38(01):104－113.
[43] 徐荣, 刘倩, 朱春晖, 等. 一种UIO-66-NH2掺杂的有机硅高盐废水处理膜及其制备方法[P]. 江苏省：　CN111298665B,　2022-02-11.
[44] 朱春晖, 徐荣, 任秀秀, 等. ZIF-8-NH2/有机硅杂化膜的制备及渗透汽化脱盐性能研究[J]. 无机材料学报, 2020, 35(11):1239－1246.
[45] Anggarini U, Yu L, Nagasawa H, et al. Structural transformation of the nickel coordination-induced subnanoporosity of aminosilica membranes for methanol-selective, high-flux pervaporation[J]. J. Membr. Sci., 2022, 656:120613.

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