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二维沸石纳米片的合成及其分离膜研究现状

作者：李艳美，魏嫣莹，王海辉

单位： 1.华南理工大学化学与化工学院，绿色化学产品技术广东省重点实验室，广州510000 2.清华大学化学工程系，膜技术与工程研究中心，北京100084

关键词：膜分离；二维膜；沸石纳米片

DOI号：

分类号： TQ028.8

出版年,卷(期):页码： 2023,43(6):139-148

摘要：

二维（2D）纳米片堆叠构建的层状分离膜的出现为下一代高效膜分离技术开辟了新途径。2D沸石纳米片具有纳米级别的厚度及较大的横纵比，其面内规整孔道为分子传质提供了丰富的路径，并可有效缩短传统无孔纳米片堆叠构筑的二维膜内分子绕行的传质路径，有望用于制备具有优异分离性能的二维材料膜。本文综述了2D沸石纳米片的合成方法及沸石纳米片膜的研究进展，重点介绍了2D沸石纳米片合成方法，包括表面活性剂辅助合成、沸石层状前驱体剥离和Assembly - disassembly - organization - reassembly（ADOR）法，以及2D沸石纳米片膜的制备方法及其在膜分离中的应用，最后对该领域当前的技术局限性和未来的研究方向进行展望。

The emergence of two-dimensional (2D) nanosheet stacks of laminar membranes open up new avenue for next-generation high-efficiency membrane separation technologies. 2D zeolite nanosheets with nanoscale thickness and large aspect ratios have regular in-plane pore channels that provide a amount of pathways for molecules, and they can effectively shorten the mass transfer path of molecules bypassing nanosheets within the 2D membranes constructed by stacking traditional non-porous nanosheet, which are expected to be used for the preparation of 2D membranes with excellent separation performance. In this review, we discuss the recent breakthrough progress of synthesis methods of 2D zeolite nanosheets and zeolite nanosheet-based membranes, focusing on 2D zeolite nanosheet synthesis methods, including surfactant-assisted synthesis of nanosheet zeolites, precursor detemplation synthesis of nanosheet zeolites, and Assembly - Disassembly - Organization - Reassembly strategy (ADOR) synthesis of nanosheet zeolites, as well as the preparation methods of 2D zeolite nanosheet-based membranes and their applications in membrane separations. Finally, an outlook analysis was made on the current technological limitations and future research directions in this field.

基金项目：

国家重点研发计划青年科学家项目（2021YFB3802500）；国家自然科学基金项目（22022805和22078107），制浆造纸工程国家重点实验室培育项目（2022PY04），中央高校基本业务费（2022ZYGXZR010）

作者简介：

李艳美（1995-），女，山东德州人，博士生，研究方向为二维沸石膜分离，E-mail：1159867560@qq.com.

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