垃圾渗滤液膜滤浓缩液膜蒸馏减量技术研究
作者:李枫,贾晓琳,王瑞婧,姚鸣铎,侯得印
单位: 1. 中国科学院生态环境研究中心,工业废水无害化与资源化国家工程研究中心,北京100085;2. 中国科学院大学,北京100049
关键词: 渗滤液;气隙膜蒸馏;膜滤浓缩液;膜蒸馏减量
DOI号:
分类号: X52;TQ319
出版年,卷(期):页码: 2024,44(1):114-122

摘要:
 垃圾渗滤液膜滤浓缩液的高效处理已成为市政与环境污染治理领域的迫切需求。本研究以北京市某垃圾填埋场的渗滤液膜滤浓缩液为研究对象,采用“预处理-气隙膜蒸馏”组合工艺对其进行减量化处理。我们研究了不同组合工艺对浓缩液处理效果的影响,发现从实用性角度考虑,混凝沉淀预处理对于浓缩液的减量化过程具有最佳的运维保障效果,可将垃圾渗滤液膜滤浓缩液减少80%以上。本研究发现合适的预处理可以显著降低膜污染,从而直接影响膜蒸馏膜通量的稳定性和对浓缩液的体积减量率。
 The efficient treatment of concentrated leachate has become an urgent need in the field of municipal and environmental pollution control. In this study, the concentrated leachate from a garbage landfill in Beijing was taken as the research object, and a combination process of "pretreatment-air gap membrane distillation" was used for its reduction treatment. We studied the effects of different combination processes on the treatment efficiency of the concentrated leachate. From a practical perspective, coagulation and precipitation pretreatment has the best operational guarantee effect on the reduction process of the concentrated leachate, and can reduce the concentrated leachate of garbage by more than 80%. We found that suitable pretreatment can significantly reduce membrane fouling, thereby directly affecting the stability of membrane distillation permeation flux and the volume reduction rate of the concentrated leachate.

基金项目:
国家重点研发计划项目(2023YFC3207002),国家自然科学基金面上项目(51978650)

作者简介:
李枫(1988-),男,山东肥城,助理研究员,工学博士,膜法工业废水处理及资源化,E-mail:fengli@rcees.ac.cn

参考文献:
 [1] Renou S, Givaudan J G, Poulain S, et al. Landfill leachate treatment: Review and opportunity [J]. Journal of Hazardous Materials, 2008, 150: 468-493.
[2] Wiszniowski J, Robert D, Surmacz-Gorska J, et al. Landfill leachate treatment methods: A review [J]. Environmental Chemisry Letters, 2006, 4: 51-61.
[3] 兰吉武,詹良通,李育超,等. 填埋垃圾初始含水率对渗滤液产量的影响即修正渗滤液产量计算公式 [J]. 环境科学,2012,33:1389-1396.
[4] Cassano D, Zapata A, Brunetti G, et al. Comparison of several combined/integrated biological-AOPs setups for the treatment of municipal landfill leachate: Minimization of operating costs and effluent toxicity [J]. Chemical Engineering Journal, 2011, 172: 250-257.
[5] Hunce S Y, Akgul D, Demir G, et al. Solidification/stabilization of landfill leachate concentrate using different aggregate materials [J]. Waste Management, 2012, 32: 1394-1400.
[6] Shah T M, Ramaswami S, Behrendt J, et al. Simultaneous removal of organics and ammonium-nitrogen from reverse osmosis concentrate of mature landfill leachate [J]. Journal of Water Process Engineering, 2017, 19: 126-132.
[7] Hu Y, Lu Y, Liu G, et al. 2018. Effect of the structure of stacked electro-Fenton reactor on treating nanofiltration concentrate of landfill leachate [J]. Chemosphere, 2018, 202: 191-197.
[8] Sepehri A, Sarrafzadeh M H. Effect of nitrifiers community on fouling mitigation and nitrification efficiency in a membrane bioreactor [J]. Chemical Engineering Journal, 2018 128: 10-18.
[9] Zolfaghari M, Droguia P, Brar S K, et al. 2016. Effect of bioavailability on the fate of hydrophobic organic compounds and metal in treatment of young landfill leachate by membrane bioreactor [J]. Chemosphere,2016, 161: 390-399.
[10] 胡云飞. 基于短程硝化反硝化MBR+RO处理垃圾渗滤液的应用研究[D].浙江农林大学,2019.
[11] Fernandes A, Chamem O, Pacheco M J, et al. Performance of Electrochemical Processes in the Treatment of Reverse Osmosis Concentrates of Sanitary Landfill Leachate [J]. Molecules, 2019, 24: 2905.
[12] Amin M, Lou Z Y, Wang H, et al. Concentrated landfill leachate treatment with a combined system including electro-ozonation and composite adsorbent augmented sequencing batch reactor process [J]. Process Safety and Environmental Protection, 2017, 111: 253-262.
[13] Zhou B, Yu Z M, Wei Q P, et al. Electrochemical oxidation of biological pretreated and membrane separated landfill leachate concentrates on boron doped diamond anode [J]. Applied Surface Science, 2016, 377: 406-415.
[14] Chen W M, Gu Z P, Wen P, et al. Degradation of refractory organic contaminants in membrane concentrates from landfill leachate by a combined coagulation-ozonation process [J]. Chemosphere, 2019, 217: 411-422.
[15] 李景义. 纳滤和反渗透技术用于盐化工废水回用的研究[D].天津科技大学,2011.
[16] Ye W Y, Liu H W, Jiang M, et al. Sustainable management of landfill leachate concentrate through recovering humic substance as liquid fertilizer by loose nanofiltration [J]. Water Research, 2019, 157: 555-563.
[17] 田宝虎.渗滤液膜滤浓缩液回灌对填埋场稳定化的影响研究[D].浙江大学, 2015.
[18] 刘研萍,李秀金,王宝贞,等.渗滤液的反渗透浓缩液回灌研究[J].环境工程,2008,26:89-93.
[19] 蒋宝军,李俊生,杨威,等.垃圾渗滤液反渗透浓缩液回灌处理中试研究[J].哈尔滨商业大学学报(自然科学版),2006,06:36-40.
[20] Calabrò P S, Sbaffoni S, Orsi S, et al. The landfill reinjection of concentrated leachate: findings from a monitoring study at an Italian site [J]. Journal of Hazadous Materials, 2010, 181, 962-968.
[21] 康立刚.蒸发技术在膜过滤浓缩液处理中的应用[J].中国环保产业,2016,44-46.
[22] 戚二兵,黄亚继,袁琦,等.接触式蒸发处理垃圾渗滤液膜浓缩液试验研究[J].工业水处理,2021,41:38-42.
[23] 丁兆勇,宋薇,尹水娥,等.几种蒸发浓缩渗沥液膜浓缩液的工艺对比分析[J].环境卫生工程,2017,25(06):60-62.
[24] 岳东北,许玉东,何亮,等.浸没燃烧蒸发工艺处理浓缩渗滤液[J].中国给水排水,2005(07):71-73.
[25] 王心月. 浸没燃烧蒸发对渗滤液有机物特性及镉络合潜力影响研究[D].清华大学,2017.
[26] Fernandes A, Labiadh L, Ciríaco, L, et al. Electro-Fenton oxidation of reverse osmosis concentrate from sanitary landfill leachate: Evaluation of operational parameters [J]. Chemosphere, 2017, 184: 1223-1229.
[27] Chen W M, Zhang A P, Gu Z P, et al. Enhanced degradation of refractory organics in concentrated landfill leachate by Fe0/H2O2 coupled with microwave irradiation [J]. Chemical Engineering Journal, 2018, 354: 680-691.
[28] Lawson K W, Lloyd D R, Membrane distillation [J]. Journal of Membrane Science, 1997, 124: 1–25.
[29]El-Bourawi M S, Ding Z, Ma R, et al. A framework for better understanding membrane distillation separation process [J]. Journal of Membrane Science, 2006, 285: 4-29.
[30] Blanco Gálvez J, García-Rodríguez L, Martín-Mateos I. Seawater desalination by an innovative solar-powered membrane distillation system: the MEDESOL project [J]. Desalination,2009, 246: 567–576.
 
[31] Lin P J, Yang M C, Li Y L, et al. Prevention of surfactant wetting with agarose hydrogel layer for direct contact membrane distillation used in dyeing wastewater treatment [J]. Journal of Membrane Science, 2015, 475: 511-520.
[32] Mokhtar N M, Lau W J, Ismail A F. Dye wastewater treatment by direct contact membrane distillation using polyvinylidene fluoride hollow fiber membranes [J]. Journal of Polymer Engineering, 2015, 35: 471-479.
[33] Martinetti C R, Childress A E , Cath T Y. High recovery of concentrated RO brines using forward osmosis and membrane distillation [J]. Journal of Membrane Science, 2009, 331: 31-39.
[34] Duong H C, Gray S, Duke M, et al. Scaling control during membrane distillation of coal seam gas reverse osmosis brine [J]. Journal of Membrane Science, 2015, 493: 673-682.
[35] Srisurichan S, Jiraratananon R, Fane A G. Humic acid fouling in the membrane distillation process [J]. Desalination, 2005, 174: 63-72.
[36] Tipping, E. Cation Binding by Humic Substances [M]. Cambridge, Cambridge University Press, 2002: 434.
[37] Rey-Castro C, Mongin S, Huidobro, C, et al. Effective affinity distribution for the binding of metal ions to a generic fulvic acid in natural waters [J]. Environmental Science & Technology, 2009, 43: 7184-7191.

服务与反馈:
文章下载】【加入收藏

《膜科学与技术》编辑部 地址:北京市朝阳区北三环东路19号蓝星大厦 邮政编码:100029 电话:010-64426130/64433466 传真:010-80485372邮箱:mkxyjs@163.com

京公网安备11011302000819号