疏水微孔膜蒸馏膜的应用进展
作者:徐浩然,张娜,张娇娇,陈越,王志宁
单位: 1山东大学 环境科学与工程学院,青岛 266237;2 山东东岳高分子材料有限公司 含氟功能膜材料国家重点实验室,淄博 256401
关键词: 膜蒸馏;疏水膜;膜改性;脱盐;废水处理
DOI号:
分类号: TQ028.8
出版年,卷(期):页码: 2024,44(1):137-146

摘要:
 膜蒸馏作为一种热法与膜法耦合的高效分离技术,在海水淡化、工业废水处理等多个领域都具有广阔的应用前景。然而膜蒸馏在实际应用中存在疏水膜的润湿、污染、结垢等瓶颈,以及能量利用效率低、实际通量低等问题,尚未得到大规模的应用推广。本文从膜蒸馏技术的简要介绍出发,总结了膜蒸馏技术的发展历程。之后综述了膜蒸馏技术在国内外企业的商业应用情况,分析了疏水微孔膜蒸馏膜在多个水处理领域的应用潜力。最后总结了制约膜蒸馏应用的主要问题,并探讨了膜蒸馏的未来发展方向。
 Membrane distillation, as an efficient separation technology coupled with thermal and membrane methods, has broad application prospects in multiple fields such as seawater desalination and industrial wastewater treatment. However, membrane distillation faces bottlenecks such as wetting, fouling, and scaling of hydrophobic membranes in application, as well as low energy utilization efficiency and actual flux. Therefore, membrane distillation has not yet been widely applied and promoted. This article starts with a brief introduction to membrane distillation technology and summarizes the development process of membrane distillation technology. Afterwards, we reviewed the commercial applications of membrane distillation technology in domestic and foreign enterprises and analyzed the potential applications of hydrophobic microporous membrane distillation membranes in multiple water treatment fields. Finally, the main issues that constrain the application of membrane distillation were summarized, and the future development direction of membrane distillation was discussed.

基金项目:
国家自然科学基金面上项目(22078175);中国博士后科学基金面上项目(2022M721926);山东省自然科学基金项目(ZR2021LFG010、ZR2022QB168);山东能源研究院企业联合基金项目(SEI U202302)

作者简介:
徐浩然(2001-),男,山东日照人,硕士研究生,研究方向为中空纤维膜蒸馏膜,Email: 202332962@mail.sdu.edu.cn.

参考文献:
 [1] 林旭, 刘彩虹, 刘乾亮, 等. 膜蒸馏技术处理工业废水研究进展 [J]. 中国给水排水, 2022, 38(10): 46-55.
[2] 吴庸烈. 膜蒸馏技术及其应用进展 [J]. 膜科学与技术, 2003, (04): 67-79+92.
[3] 王军, 李魁岭, 王樟新, 等. 膜蒸馏技术疏水膜、组件及工艺研究进展 [J]. 环境工程, 2021, 39(07): 13-29+191.
[4] Aijaz M O, Karim M R, Othman M H D, et al. Anti-fouling/wetting electrospun nanofibrous membranes for membrane distillation desalination: A comprehensive review [J]. Desalination, 2023, 553: 116475.
[5] Zhang N, Zhang J, Yang X, et al. Janus Membrane with Hydrogel-like Coating for Robust Fouling and Wetting Resistance in Membrane Distillation [J]. ACS Applied Materials & Interfaces, 2023, 15(15): 19504-19513.
[6] Bodell B R. Silicone rubber vapor diffusion in saline water distillation [P]. US Pat, US00285032A. 1963.
[7] Bodell B R. Distillation of saline water using silicone rubber membrane [P]. US Pat, US3361645A. 1968-01-02.
[8] Cheng D Y, Wiersma S J. Composite membrane for a membrane distillation system [P]. US Pat, US4316772A. 1982-02-03.
[9] Cheng D Y, Wiersma S J. Apparatus and method for thermal membrane distillation [P]. US Pat, US4419187A. 1983-12-06.
[10] Andersson S I, Kjellander N, Rodesjö B. Design and field tests of a new membrane distillation desalination process [J]. Desalination, 1985, 56: 345-354.
[11] Schneider K, Hölz W, Wollbeck R, et al. Membranes and modules for transmembrane distillation [J]. Journal of Membrane Science, 1988, 39(1): 25-42.
[12] Thomas N, Mavukkandy M O, Loutatidou S, et al. Membrane distillation research & implementation: Lessons from the past five decades [J]. Separation and Purification Technology, 2017, 189: 108-127.
[13] 高启君, 吕晓龙, 刘超, 等. 减压组合气隙膜蒸馏方法及其装置 [P]. 中国专利, CN104190260B. 2016-01-20.
[14] 吕晓龙. 膜蒸馏过程探讨 [J]. 膜科学与技术, 2010, 30(03): 1-10.
[15] Zhao K, Heinzl W, Wenzel M, et al. Experimental study of the memsys vacuum-multi-effect-membrane-distillation (V-MEMD) module [J]. Desalination, 2013, 323: 150-160.
[16] Xu G-R, Wang M, Xu K, et al. Membrane fabrication and configuration design development of photothermal membrane distillation (PMD) [J]. Desalination, 2023, 565: 116833.
[17] González D, Amigo J, Suárez F. Membrane distillation: Perspectives for sustainable and improved desalination [J]. Renewable and Sustainable Energy Reviews, 2017, 80: 238-259.
[18] 李伟. 高通量管式膜蒸馏组件结构设计及污酸处理研究 [D]. 北京:北京有色金属研究总院, 2019.
[19] Jeong S, Lee S, Chon H-T, et al. Structural analysis and modeling of the commercial high performance composite flat sheet membranes for membrane distillation application [J]. Desalination, 2014, 349: 115-125.
[20] Winter D, Koschikowski J, Wieghaus M. Desalination using membrane distillation: Experimental studies on full scale spiral wound modules [J]. Journal of Membrane Science, 2011, 375(1): 104-112.
[21] Shafieian A, Khiadani M, Zargar M. Performance analysis of tubular membrane distillation modules: An experimental and CFD analysis [J]. Chemical Engineering Research and Design, 2022, 183: 478-493.
[22] Pang Z, Hou C, Xie S, et al. Optimization of hollow fiber membrane module for vacuum membrane distillation (VMD) via experimental study [J]. Desalination, 2022, 542: 116068.
[23] Jansen A E, Assink J W, Hanemaaijer J H, et al. Development and pilot testing of full-scale membrane distillation modules for deployment of waste heat [J]. Desalination, 2013, 323: 55-65.
[24] Pryor T. Tjuntjuntjara remote inland indigenous community solar/waste energy groundwater desalination project[C]//NCEDA international desalination workshop, 2013.
[25] Zhani K, Zarzoum K, Ben Bacha H, et al. Autonomous solar powered membrane distillation systems: state of the art [J]. Desalination and Water Treatment, 2016, 57(48-49): 23038-23051.
[26] Raluy R G, Schwantes R, Subiela V J, et al. Operational experience of a solar membrane distillation demonstration plant in Pozo Izquierdo-Gran Canaria Island (Spain) [J]. Desalination, 2012, 290: 1-13.
[27] Minier-Matar J, Hussain A, Janson A, et al. Field evaluation of membrane distillation technologies for desalination of highly saline brines [J]. Desalination, 2014, 351: 101-108.
[28] 中国膜工业协会. 新疆德蓝在南疆岳普湖县苦咸水淡化示范工程建成通水 [EB/OL]. [2023-09-19]. http://www.membranes.com.cn/xingyedongtai/xiehuidongtai/2015-01-19/4326.html. 
[29] Duong H C, Cooper P, Nelemans B, et al. Evaluating energy consumption of air gap membrane distillation for seawater desalination at pilot scale level [J]. Separation and Purification Technology, 2016, 166: 55-62.
[30] 中国膜工业协会. 湖州森诺膜蒸馏成功用于垃圾焚烧飞灰水泥窑协同处置 [EB/OL]. [2023-09-19]. http://www.membranes.com.cn/xingyedongtai/xiehuidongtai/2016-08-25/26607.html. 
[31] 贤集网. 博天环境旗下中环膜毕飞:瞄准方向,专注膜法水处理应用 [EB/OL]. [2023-09-19]. https://www.xianjichina.com/special/detail_360125.html. 
[32] 北京中科瑞升资源环境技术有限公司. 北京中科瑞升江苏高浓度废酸浓缩项目稳定运行 [EB/OL]. [2023-09-19]. http://www.csretech.com.cn/NewsDetail/501299.html. 
[33] 吴英来, 郭政伟. 膜蒸馏技术在稀硫酸回收中的应用 [J]. 硫酸工业, 2022, (10): 26-28.
[34] 陈明玉, 唐娜, 袁建军. 膜蒸馏海水及苦咸水淡化研究进展 [J]. 盐业与化工, 2006, (06): 18-21.
[35] Yang X, Zhang N, Zhang J, et al. Nanocomposite Hydrogel Engineered Janus Membrane for Membrane Distillation with Robust Fouling, Wetting, and Scaling Resistance [J]. Environmental Science & Technology, 2023, 57(41): 15725-15735.
[36] 余辉, 孙聪聪, 焦少俊, 等. 废酸的综合治理与资源化研究进展 [J]. 环境监测管理与技术, 2018, 30(02): 5-10.
[37] 高永钢, 王鹏, 苏成龙, 等. 膜蒸馏技术在污酸处置领域的工程化应用 [J]. 硫酸工业, 2022, (11): 24-28+33.
[38] 李建国, 李剑锋, 任静, 等. 超疏水疏油改性PVDF膜用于膜蒸馏深度处理焦化废水 [J]. 水处理技术, 2018, 44(03): 58-62+68.
[39] 高亚楠, 黄满红, 陈东辉, 等. PCH电纺MD膜处理高盐印染废水的性能研究 [J]. 水处理技术, 2022, 48(06): 58-62.
[40] Huang M, Song J, Deng Q, et al. Novel electrospun ZIF/PcH nanofibrous membranes for enhanced performance of membrane distillation for salty and dyeing wastewater treatment [J]. Desalination, 2022, 527: 115563.
[41] 武春瑞, 刘东, 陈华艳, 等. PVDF疏水中空纤维膜的膜蒸馏含盐废水处理性能研究 [J]. 功能材料, 2008, 39(12): 2018-2021.
[42] Du X, Zhang Z, Carlson K H, et al. Membrane fouling and reusability in membrane distillation of shale oil and gas produced water: Effects of membrane surface wettability [J]. Journal of Membrane Science, 2018, 567: 199-208.
[43] Fang C, Garcia-Rodriguez O, Shang C, et al. An omniphobic membrane with macro-corrugation for the treatment of real pharmaceutical wastewater via membrane distillation [J]. Journal of Membrane Science, 2023, 676: 121582.
[44] Yadav A, Yadav P, Labhasetwar P K, et al. CNT functionalized ZIF-8 impregnated poly(vinylidene fluoride-co-hexafluoropropylene) mixed matrix membranes for antibiotics removal from pharmaceutical industry wastewater by vacuum membrane distillation [J]. Journal of Environmental Chemical Engineering, 2021, 9(6): 106560.
[45] Zico M M, Ricci B C, Reis B G, et al. Sustainable ammonia resource recovery from landfill leachate by solar-driven modified direct contact membrane distillation [J]. Separation and Purification Technology, 2021, 264: 118356.
[46] Zhou L, Zhang H, Ahmad A L, et al. Hierarchical structure design of electrospun membrane for enhanced membrane distillation treatment of shrimp aquaculture wastewater [J]. Separation and Purification Technology, 2023, 306: 122591.
[47] 金畅, 喻翠云, 肖德涛, 等. 气隙式膜蒸馏处理模拟放射性废水 [J]. 核化学与放射化学, 2015, 37(01): 45-50.
[48] Korolkov I V, Yeszhanov A B, Zdorovets M V, et al. Modification of PET ion track membranes for membrane distillation of low-level liquid radioactive wastes and salt solutions [J]. Separation and Purification Technology, 2019, 227: 115694.
[49] 沈鑫. 真空膜蒸馏法处理焦化废水的研究 [D]. 镇江:江苏大学, 2020.
[50] 胡景泽, 王庆吉, 谢加才, 等. 石油石化含盐有机废水脱盐处理技术及资源化研究进展 [J]. 工业水处理: 1-21.
[51] 徐晴, 王健, 温官. 平板陶瓷膜深度处理石化废水试验研究 [J]. 能源环境保护, 2020, 34(02): 25-29.
[52] 李彬, 张晨阳, 陶伟伟. 制药废水处理技术研究进展 [J]. 工业水处理, 2022, 42(11): 7-17.
[53] 刘爽, 李彩莲, 常明庆. 中药提取类制药废水处理工艺研究与工程应用 [J]. 造纸装备及材料, 2022, 51(06): 133-135.
[54] Chen X, Chen T, Li J, et al. Ceramic nanofiltration and membrane distillation hybrid membrane processes for the purification and recycling of boric acid from simulative radioactive waste water [J]. Journal of Membrane Science, 2019, 579: 294-301.

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